(1-Methyl-2-methylidenecyclopropyl)benzene

Base Information

Chemical Name:(1-Methyl-2-methylidenecyclopropyl)benzene
CAS No.:105486-60-0
Molecular Formula:C₁₁H₁₂
Molecular Weight:144.216
Hs Code.:
DSSTox Substance ID:DTXSID20557541
Nikkaji Number:J1.689.394C
Mol file:105486-60-0.mol

Synonyms:(1-Methyl-2-methylidenecyclopropyl)benzene;105486-60-0;DTXSID20557541

Suppliers and Price of (1-Methyl-2-methylidenecyclopropyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (1-Methyl-2-methylidenecyclopropyl)benzene

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:144.093900383
Heavy Atom Count:11
Complexity:175

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CC1=C)C2=CC=CC=C2

Technology Process of (1-Methyl-2-methylidenecyclopropyl)benzene

There total 6 articles about (1-Methyl-2-methylidenecyclopropyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1192138-21-8
(2-methylcycloprop-1-enyl)methanol

: 16002-63-4
phenylmagnesium iodide

: 22664-15-9,105486-60-0
2-methyl-2-phenyl-1-methylidencyclopropane

Guidance literature:: With copper(l) iodide; In diethyl ether; at -50 - 20 ℃; for 9h;
DOI:10.1002/chem.200901074

Reference yield:

: 107432-61-1
(2-Bromo-1,2-dimethyl-cyclopropyl)-benzene

: 22664-15-9,105486-60-0
2-methyl-2-phenyl-1-methylidencyclopropane

Guidance literature:: With potassium tert-butylate; In dimethyl sulfoxide; at 20 ℃;
DOI:10.1021/ja9046894

Reference yield:

: 17343-73-6
(2,2-dibromo-1-methylcyclopropyl)benzene

: 22664-15-9,105486-60-0
2-methyl-2-phenyl-1-methylidencyclopropane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / -95 °C

1.2: -95 - 20 °C

2.1: potassium tert-butylate / dimethyl sulfoxide / 20 °C

With n-butyllithium; potassium tert-butylate; In tetrahydrofuran; hexane; dimethyl sulfoxide;
DOI:10.1021/ja9046894