bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate

Base Information

• Chemical Name: bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate
• CAS No.: 618384-02-4
• Molecular Formula: C₆H₆*C₃₂H₉₆Fe₃N₂O₄Si₁₂
• Molecular Weight: 1155.81
• Mol file: 618384-02-4.mol

Synonyms:

Chemical Property of bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate

There total 1 articles about bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

iron(II) bis(trimethylsilyl)amide (14760-22-6) + pentamethyldisilanol (18135-02-9) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → bis[bis(trimethylsilylamino)tetrakis(μ2-pentamethyldisiloxy)]triiron benzenemonosolvate (618384-02-4)

Guidance literature:

In hexane; (Ar); addn. of soln. of pentamethyldisalanol (4 equiv.) in hexane to soln. of ((Me3Si)2N)2Fe (3 equiv.) in hexane; heating at 50°C for 3 h; crystn. from benzene-hexane (1:1) mixt. by slow cooling of the warm soln. to 20°C; decanting of mother liquor, removal of solvent residues in Ar flow; elem. anal.;

DOI:10.1023/A:1023423202997

upstream raw materials:

iron(II) bis(trimethylsilyl)amide

pentamethyldisilanol

benzene