Technology Process of Dimethyl meso-2,2'-dimethyl-4,4'-diphenyl-2,2'-azobutanoate
There total 5 articles about Dimethyl meso-2,2'-dimethyl-4,4'-diphenyl-2,2'-azobutanoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 100 percent / 30percent aq. NH4OH, NH3-gas / methanol / 1) 0 deg C, 2 h 2) r.t., 4 d
2: 80 percent / conc. HCl / 48 h / Heating
3: 95 percent / SOCl2 / 240 h / Ambient temperature
4: SO2Cl2 / pentane / 0.25 h / 0 °C
5: 1) NaOMe 2) t-BuOCl / 1) MeOH, 0 deg C, 0.5 h 2) MeOH, 0 deg C, 1 h
With
hydrogenchloride; ammonium hydroxide; thionyl chloride; sulfuryl dichloride; tert-butylhypochlorite; sodium methylate;
In
methanol; pentane;
DOI:10.1021/jo00006a014
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 80 percent / conc. HCl / 48 h / Heating
2: 95 percent / SOCl2 / 240 h / Ambient temperature
3: SO2Cl2 / pentane / 0.25 h / 0 °C
4: 1) NaOMe 2) t-BuOCl / 1) MeOH, 0 deg C, 0.5 h 2) MeOH, 0 deg C, 1 h
With
hydrogenchloride; thionyl chloride; sulfuryl dichloride; tert-butylhypochlorite; sodium methylate;
In
pentane;
DOI:10.1021/jo00006a014
- Guidance literature:
-
Multi-step reaction with 2 steps
1: SO2Cl2 / pentane / 0.25 h / 0 °C
2: 1) NaOMe 2) t-BuOCl / 1) MeOH, 0 deg C, 0.5 h 2) MeOH, 0 deg C, 1 h
With
sulfuryl dichloride; tert-butylhypochlorite; sodium methylate;
In
pentane;
DOI:10.1021/jo00006a014
