[(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf

Base Information

• Chemical Name: [(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf
• CAS No.: 1242584-00-4
• Molecular Formula: CF₃O₃S*C₅₀H₃₂CrF₆N₄O₆S₂
• Molecular Weight: 1164.02
• Mol file: 1242584-00-4.mol

Synonyms:

Chemical Property of [(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf

There total 1 articles about [(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

trifluorormethanesulfonic acid (1493-13-6) + [(4,7-diphenyl-1,10-phenanthroline)2CrCl2]Cl (1242583-98-7) → [(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf (1242584-00-4)

Guidance literature:

In neat (no solvent); under N2 atm. CF3SO3H was slowly added to solid Cr-complex, N2 was bubbled through the stirring soln. for 24 h; cooled in an ice bath, diethyl ether was added, allowed to stand for 4 h, ppt. was vac.-filtered, rinsed with diethyl ether;

DOI:10.1021/ic1009972

Reference yield:

[(4,7-diphenyl-1,10-phenanthroline)2Cr(OTf)2]OTf (1242584-00-4) + bathophenanthroline (1662-01-7) → [Cr(4,7-diphenyl-1,10-phenanthroline)3](CF3SO3)3

Guidance literature:

In dichloromethane; the soln. of complex and 5 equiv of phenanthroline-compound in CH2Cl2 was refluxed for 16 h; ppt. was filtered;

DOI:10.1021/ic1009972

upstream raw materials:

trifluorormethanesulfonic acid

[(4,7-diphenyl-1,10-phenanthroline)2CrCl₂]Cl