thallium 4-tert-butylphenoxide

Base Information

• Chemical Name: thallium 4-tert-butylphenoxide
• CAS No.: 117371-33-2
• Molecular Formula: C₁₀H₁₃OTl
• Molecular Weight: 353.596
• Mol file: 117371-33-2.mol

Synonyms:

Chemical Property of thallium 4-tert-butylphenoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of thallium 4-tert-butylphenoxide

There total 1 articles about thallium 4-tert-butylphenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

para-tert-butylphenol (98-54-4) + thallium (I) ethoxide (20398-06-5) → thallium 4-tert-butylphenoxide (117371-33-2)

Guidance literature:

In tetrahydrofuran; pentane; phenol was dissolved in pentane and minimumamt. THF and treated with soln. thallium ethoxide in pentane, mixt. was stirred for 2 h; solid was filtered off, washed with pentane and dried in vacuo; elem. anal.;

DOI:10.1021/ic010615c

Reference yield: 76.0%

NiCl(C6H5B(CH2P(C6H5)2)3) (741735-75-1) + thallium 4-tert-butylphenoxide (117371-33-2) → Ni(OC(CH3)3C6H4)(C6H5B(CH2P(C6H5)2)3)

Guidance literature:

In tetrahydrofuran; byproducts: TlCl; under N2; soln. of Tl-salt in THF was added to stirred soln. of Ni-complex in THF, stirred for 3 h; concd. under reduced pressure, extd. with benzene, filtered, vapor diffusion of petrolem ether into benzene soln.; elem. anal.;

DOI:10.1021/ic049936p

Reference yield: 66.0%

(2,4-bis((2,6-diisopropylphenyl)imido)pentane)CuCl (245758-58-1) + thallium 4-tert-butylphenoxide (117371-33-2) → (2,4-((2,6-diisopropylphenyl)imido)pentane)Cu(4-tert-butylphenoxide) (380429-33-4)

Guidance literature:

In tetrahydrofuran; under N2 atm. soln. Cu(II) complex in THF was treated with thallium phenoxide salt as solid and stirred for 1 h; filtrate was evapd. to dryness, residue was redissolved in pentane, filtered and concd.; elem. anal.;

DOI:10.1021/ic010615c

upstream raw materials:

para-tert-butylphenol

thallium (I) ethoxide

Downstream raw materials:

(2,4-((2,6-diisopropylphenyl)imido)pentane)Cu(4-tert-butylphenoxide)

(2,4-((2,6-diisopropylphenyl)imido)-3-chloropentane)Cu(4-tert-butylphenoxide)