C₅₀H₆₇NO₁₁

Base Information

• Chemical Name: C₅₀H₆₇NO₁₁
• CAS No.: 1380242-25-0
• Molecular Formula: C₅₀H₆₇NO₁₁
• Molecular Weight: 858.082
• Mol file: 1380242-25-0.mol

Synonyms:

Chemical Property of C₅₀H₆₇NO₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₀H₆₇NO₁₁

There total 18 articles about C₅₀H₆₇NO₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C22H34O4 (1380242-06-7) + C30H37NO7 (1380242-05-6) → C50H67NO11 (1380242-25-0) + C50H67NO11 (1380242-20-5)

Guidance literature:

With Hoveyda-Grubbs catalyst second generation; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1002/anie.201201395

Reference yield:

C25H31NO4S (1380242-15-8) → C50H67NO11 (1380242-25-0) + C50H67NO11 (1380242-20-5)

Guidance literature:

Multi-step reaction with 9 steps

1.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C

2.1: diisobutylaluminium hydride / dichloromethane; cyclohexane / 3 h / -78 °C / Inert atmosphere

3.1: titanium tetrachloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 4 h / -78 °C / Inert atmosphere

4.1: trimethylaluminum / dichloromethane; toluene / 0.5 h / -10 - 20 °C / Inert atmosphere

4.2: 8 h / -10 °C / Inert atmosphere

5.1: methyllithium / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C / Inert atmosphere

5.2: 2 h / -78 °C / Inert atmosphere

6.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 17 h / -30 - -15 °C / Inert atmosphere

7.1: toluene-4-sulfonic acid / acetone / 16 h / 20 °C

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 80 °C

9.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 24 h / 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; Hoveyda-Grubbs catalyst second generation; tetramethylammonium triacetoxyborohydride; tetrabutyl ammonium fluoride; methyllithium; trimethylaluminum; titanium tetrachloride; diisobutylaluminium hydride; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; cyclohexane; acetone; toluene; acetonitrile;

DOI:10.1002/anie.201201395

Reference yield:

C31H45NO4SSi (1380242-16-9) → C50H67NO11 (1380242-25-0) + C50H67NO11 (1380242-20-5)

Guidance literature:

Multi-step reaction with 8 steps

1.1: diisobutylaluminium hydride / dichloromethane; cyclohexane / 3 h / -78 °C / Inert atmosphere

2.1: titanium tetrachloride; N-ethyl-N,N-diisopropylamine / dichloromethane / 4 h / -78 °C / Inert atmosphere

3.1: trimethylaluminum / dichloromethane; toluene / 0.5 h / -10 - 20 °C / Inert atmosphere

3.2: 8 h / -10 °C / Inert atmosphere

4.1: methyllithium / tetrahydrofuran; diethyl ether / 0.5 h / -78 °C / Inert atmosphere

4.2: 2 h / -78 °C / Inert atmosphere

5.1: tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 17 h / -30 - -15 °C / Inert atmosphere

6.1: toluene-4-sulfonic acid / acetone / 16 h / 20 °C

7.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 80 °C

8.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 24 h / 20 °C / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; tetramethylammonium triacetoxyborohydride; tetrabutyl ammonium fluoride; methyllithium; trimethylaluminum; titanium tetrachloride; diisobutylaluminium hydride; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; diethyl ether; dichloromethane; cyclohexane; acetone; toluene; acetonitrile;

DOI:10.1002/anie.201201395

upstream raw materials:

C₁₅H₃₀OS₂Si

C₂₂H₃₄O₄

C₃₀H₃₇NO₇

C₁₆H₁₉NO₃S