trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

Base Information

Chemical Name:trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten
CAS No.:298704-92-4
Molecular Formula:C₃₈H₃₅ClO₂P₂W
Molecular Weight:804.945
Hs Code.:

trans-chlorodicarbonyl(mesitylcarbyne)(P(C<sub>6</sub>H<sub>5</sub>)2CH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)2)tungsten

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Chemical Property of trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

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Technology Process of trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

There total 1 articles about trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 298704-78-6
trans-chlorodicarbonyl(mesitylcarbyne)bis(pyridine)tungsten

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 298704-92-4
trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

Guidance literature:: In dichloromethane; byproducts: C5H5N; under N2; (P(C6H5)2CH2)2 was added to a soln. of the complex in CH2Cl2,the mixt. was stirred for 3 h at 25°C; the solvent was evapd. in vac., the compd. was washed with hexane 2 times, and recrystd. from (CH2Cl2/hexane); elem. anal.;
DOI:10.1021/om000129h

Reference yield: 95.0%

: 26042-64-8
silver hexafluoroantimonate

: 298704-92-4
trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: WC(C₆H₂(CH₃)3)(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*SbF₆^(1-)*2C₆H₆=WC(C₆H₂(CH₃)3)(CO)3(P(C₆H₅)2C₂H₄P(C₆H₅)2)(SbF₆)*2C₆H₆

Guidance literature:: With CO; In dichloromethane; to a soln. of complex iin CH2Cl2 was added a soln. of AgSbF6 in CH2Cl2 under an atm. of CO at room temp., stirred for 30 min under the exclusionof light; evapd. in vac., suspnd. in benzene, filtered, the solvent was evapd. in vac., washed with hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)00864-0

Reference yield: 91.0%

: 26042-64-8
silver hexafluoroantimonate

: 298704-92-4
trans-chlorodicarbonyl(mesitylcarbyne)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)tungsten

: 343257-16-9
WC(C₆H₂(CH₃)3)(CO)2(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹⁺⁾*SbF₆^(1-)=WC(C₆H₂(CH₃)3)(CO)2(P(C₆H₅)2C₂H₄P(C₆H₅)2)(SbF₆)

Guidance literature:: In dichloromethane; byproducts: AgCl; a soln. in CH2Cl2 was stirred for 10 min under the exclusion of light (N2); the solvent was removed, suspn. in benzene, filtered, the soln. was evapd. in vac., the residue was dissolved in CH2Cl2 and pptd. with hexane; elem. anal.;
DOI:10.1016/S0022-328X(00)00864-0