(E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

Base Information

Chemical Name:(E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal
CAS No.:153899-36-6
Molecular Formula:C₁₅H₂₀O₃
Molecular Weight:248.322
Hs Code.:

Synonyms:

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Chemical Property of (E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

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Technology Process of (E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

There total 10 articles about (E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 141546-70-5
(3S,4R)-5-hydroxy-4-methoxy-3-methylpentanenitrile

: 153899-36-6
(E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

Guidance literature:: Multi-step reaction with 5 steps

1: pyridinium chlorochromate, molecular sieves / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 1.) CrCl₂, DMF / 1.) THF, RT, 30 min, 2.) THF, RT, 3 h

3: 61 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 1 h / Ambient temperature

4: DIBAL / toluene; CH₂Cl₂ / 2 h / 0 °C

5: 5percent aq. H₂SO₄ / toluene; CH₂Cl₂ / 6 h / Ambient temperature

With chromium dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; molecular sieve; sulfuric acid; diisobutylaluminium hydride; N,N-dimethyl-formamide; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; toluene;

Reference yield:

: 141546-67-0
4-O-benzoyl-2-deoxy-2-C-methyl-3-O-methyl-L-threitol

: 153899-36-6
(E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

Guidance literature:: Multi-step reaction with 8 steps

1: 94 percent / pyridine / 1 h / 0 °C

2: 100 percent / dimethylformamide / 6 h / 50 °C

3: 89 percent / NaOMe / methanol / 1 h / 0 °C

4: pyridinium chlorochromate, molecular sieves / CH₂Cl₂ / 0.5 h / Ambient temperature

5: 1.) CrCl₂, DMF / 1.) THF, RT, 30 min, 2.) THF, RT, 3 h

6: 61 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 1 h / Ambient temperature

7: DIBAL / toluene; CH₂Cl₂ / 2 h / 0 °C

8: 5percent aq. H₂SO₄ / toluene; CH₂Cl₂ / 6 h / Ambient temperature

With pyridine; chromium dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; molecular sieve; sulfuric acid; sodium methylate; diisobutylaluminium hydride; N,N-dimethyl-formamide; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 141546-71-6
(3S,4R)-4-Methoxy-3-methyl-5-oxo-pentanenitrile

: 153899-36-6
(E)-(3S,4R)-4-Methoxy-6-(4-methoxy-phenyl)-3-methyl-hex-5-enal

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) CrCl₂, DMF / 1.) THF, RT, 30 min, 2.) THF, RT, 3 h

2: 61 percent / tetrakis(triphenylphosphine)palladium⁽⁰⁾ / tetrahydrofuran / 1 h / Ambient temperature

3: DIBAL / toluene; CH₂Cl₂ / 2 h / 0 °C

4: 5percent aq. H₂SO₄ / toluene; CH₂Cl₂ / 6 h / Ambient temperature

With chromium dichloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sulfuric acid; diisobutylaluminium hydride; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; toluene;