[(η5-C5Me5)TiCl2(Ph2PN-t-Bu)]

Base Information

Chemical Name:[(η5-C5Me5)TiCl2(Ph2PN-t-Bu)]
CAS No.:861446-11-9
Molecular Formula:C₂₆H₃₄Cl₂NPTi
Molecular Weight:510.322
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Chemical Property of [(η5-C5Me5)TiCl2(Ph2PN-t-Bu)]

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Technology Process of [(η5-C5Me5)TiCl2(Ph2PN-t-Bu)]

There total 1 articles about [(η5-C5Me5)TiCl2(Ph2PN-t-Bu)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 12129-06-5
Cp*TiCl₃

: 41979-47-9
N-tert-butyl-1,1-diphenylphosphinamine

: 861446-11-9
[(η5-C5Me5)TiCl2(Ph2PN-t-Bu)]

Guidance literature:: With n-BuLi; In diethyl ether; hexane; std. Schlenk technique; soln. of BuLi in hexane was added dropwise to stired soln. of ligand in Et2O at -78°C over 10 min; mixt. was stirred for 3 h; added via cannula to soln. of Ti complex in Et2O at -78°C over 10 min; stirred overnight; solvent removed (vac.); CH2Cl2 added; stirred for 15 min; filtered; filtrate evapd.; Et2O added; hexane added; cooled to -20°C; supernatant decanted; washed (hexane); solvent removed (vac.); elem. anal.;
DOI:10.1016/j.jorganchem.2005.03.016