(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl)

Base Information

• Chemical Name: (1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl)
• CAS No.: 1114572-95-0
• Molecular Formula: C₂₈H₄₃N₄Y
• Molecular Weight: 524.582
• Mol file: 1114572-95-0.mol

Synonyms:

Chemical Property of (1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl)

There total 1 articles about (1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine (1002789-60-7) + [Y(CH2Ph)3(THF)3] (1130206-42-6,960307-89-5) → (1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl) (1114572-95-0)

Guidance literature:

In toluene; (N2); addn. of toluene soln. of amine deriv. to toluene suspn. of yttrium compd., stirring at room temp. for 30 min; filtration, concg., layering with pentane, cooling to -30°C, decantation, drying in vac., elem. anal.;

DOI:10.1021/om8004228

Reference yield: 70.0%

(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl) (1114572-95-0) + phenylacetylene (536-74-3) → [(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(phenylacetylenide)(μ-phenylacetylenide)]2 (1114572-98-3)

Guidance literature:

In toluene; byproducts: toluene; (N2); addn. of toluene soln. of yttrium compd. to phenylacetylene, keeping 30 min at room temp. and overnight at -30°C; decantation, drying in vac., elem. anal.;

DOI:10.1021/om8004228

Reference yield:

(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(η1-benzyl)(η2-benzyl) (1114572-95-0) + N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate → [(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(benzyl)][B(C6F5)4] (1114573-01-1)

Guidance literature:

In further solvent(s); byproducts: C6H5N(CH3)2, C6H5CH3; (N2); addn. of C6D5Br soln. of yttrium compd. to 1 equiv. of dimethylanilinium deriv., agitation; not isolated, detected by NMR;

DOI:10.1021/om8004228

upstream raw materials:

1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine

[Y(CH₂Ph)₃(THF)₃]

Downstream raw materials:

[(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(phenylacetylenide)(μ-phenylacetylenide)]2

[(1,4,6-trimethyl-N-(2-(pyrrolidin-1-yl)ethyl)-1,4-diazepane-6-amine(-H))Y(benzyl)][B(C₆F₅)4]