C₂₃H₂₁FeOPS

Base Information

• Chemical Name: C₂₃H₂₁FeOPS
• CAS No.: 74286-06-9
• Molecular Formula: C₂₃H₂₁FeOPS
• Molecular Weight: 432.306
• Mol file: 74286-06-9.mol

Synonyms:

Chemical Property of C₂₃H₂₁FeOPS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₃H₂₁FeOPS

There total 1 articles about C₂₃H₂₁FeOPS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

rac-1-(diphenylphosphino)-2-(hydroxymethyl)ferrocene (494205-48-0,173951-67-2,33056-73-4) + sulfur (7704-34-9) → dl-1-diphenylthiophosphinyl-2-(hydroxymethyl)ferrocene (497839-23-3,74311-53-8,74286-06-9)

Guidance literature:

In toluene; under Ar, 100 °C for 1 h; solvent was removed in vac., column chromy. (silica, CH2Cl2:MeOH=10:1, v/v);

DOI:10.1039/b204655p

Reference yield: 98.0%

dl-1-diphenylthiophosphinyl-2-(hydroxymethyl)ferrocene (497839-23-3,74311-53-8,74286-06-9) → (2-(diphenylthiophosphino)ferrocenyl)methane

Guidance literature:

With borane-THF; In tetrahydrofuran; for 70h; Inert atmosphere; Reflux;

DOI:10.1039/c9dt01006h

Reference yield: 90.0%

(Sp)-(2-thiodiphenylphosphino)hydroxymethylferrocene (74311-53-8,74286-06-9,497839-23-3) → bis[(Sp)-(2-thiodiphenylphosphino)ferrocenylmethylene]sulfane

Guidance literature:

With toluene-4-sulfonic acid; In 1,4-dioxane; at 90 ℃; for 24h; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201700645

upstream raw materials:

rac-1-(diphenylphosphino)-2-(hydroxymethyl)ferrocene

sulfur

Downstream raw materials:

[(C₅H₅)Fe(C₅H₃(P(C₆H₅)2S)CH₂C₃H₃N₂CH₃)]⁽¹⁺⁾*[BF₄]^(1-)=[(C₅H₅)Fe(C₅H₃(P(C₆H₅)2S)CH₂C₃H₃N₂CH₃)][BF₄]

[(C₅H₅)Fe(C₅H₃(P(C₆H₅)2S)CH₂C₃H₃N₂C₆H₂(CH₃)3)]⁽¹⁺⁾*[BF₄]^(1-)=[(C₅H₅)Fe(C₅H₃(P(C₆H₅)2S)CH₂C₃H₃N₂C₆H₂(CH₃)3)][BF₄]