C₆₆H₈₆N₄Ni₂

Base Information

• Chemical Name: C₆₆H₈₆N₄Ni₂
• CAS No.: 1433897-62-1
• Molecular Formula: C₆₆H₈₆N₄Ni₂
• Molecular Weight: 1052.82
• Mol file: 1433897-62-1.mol

Synonyms:

Chemical Property of C₆₆H₈₆N₄Ni₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₆H₈₆N₄Ni₂

There total 4 articles about C₆₆H₈₆N₄Ni₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + C50H62N4 (1433897-00-7) → C66H86N4Ni2 (1433897-62-1)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/om400187v

Reference yield:

2,4,6-triisopropylphenylboronic acid (154549-38-9) → C66H86N4Ni2 (1433897-62-1)

Guidance literature:

Multi-step reaction with 3 steps

1: palladium diacetate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate / toluene / 48 h / 110 °C / Inert atmosphere

2: methanol / 4 h / Reflux

3: tetrahydrofuran / 24 h / 20 °C / Inert atmosphere

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate; In tetrahydrofuran; methanol; toluene;

DOI:10.1021/om400187v

Reference yield:

6-bromo-2-pyridinecarbaldehyde (34160-40-2) → C66H86N4Ni2 (1433897-62-1)

Guidance literature:

Multi-step reaction with 3 steps

1: palladium diacetate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate / toluene / 48 h / 110 °C / Inert atmosphere

2: methanol / 4 h / Reflux

3: tetrahydrofuran / 24 h / 20 °C / Inert atmosphere

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate; In tetrahydrofuran; methanol; toluene;

DOI:10.1021/om400187v

upstream raw materials:

6-(2,4,6-triisopropylphenyl)-2-pyridinecarboxaldehyde

6-bromo-2-pyridinecarbaldehyde

2,4,6-triisopropylphenylboronic acid

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾