[Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]

Base Information

Chemical Name:[Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]
CAS No.:330836-64-1
Molecular Formula:C₁₇H₁₄CrO₃
Molecular Weight:318.292
Hs Code.:

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Chemical Property of [Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]

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Technology Process of [Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]

There total 1 articles about [Cr(CO)3(η6-7-(4-MeC6H4)C7H7)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: Tris(acetonitril)tricarbonylchrom

: 29304-88-9
7-(4-Tolyl)-1,3,5-cycloheptatrien

: 330836-64-1,37768-85-7
[Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]

Guidance literature:: In tetrahydrofuran; (N2); addn. of Cr(CO)3(NCMe)3 to soln. of CH3C6H4C7H7 in THF, warming to40°C for 0.5 h, gently reflux for 1.5 h; removal of solvent, dissolving in diethyl ether, chromy. using n-hexane-diethyl ether as eluant, reducing in vol., addn. of n-hexane, cooling to-20°C overnight, sepn. from mother liquors; isolation as exo-end o mixt.;
DOI:10.1039/b0078301

Reference yield: 76.0%

: 330836-64-1,37768-85-7
[Cr(CO)3(η6-7-(4-MeC6H4)C7H7)]

: 437-17-2
tritylium hexafluorophosphate

: [Cr(CO)3(C₇H₆C₆H₄CH₃)]⁽¹⁺⁾*PF₆^(1-)=[Cr(CO)3(C₇H₆C₆H₄CH₃)][PF₆]

Guidance literature:: In dichloromethane; methyl cyclohexane; (N2); dissolving of Cr(CO)3(CH3C6H4C7H7) in methylcyclohexane; reflux for 20 min; removal of solvent in vac., dissolving in CH2Cl2, addn. of (Ph3C)(PF6); stirring for 1 h; pptn., filtration, washing with diethyl ether, drying; elem anal.;
DOI:10.1039/b0078301