(Z)-PhCHCHGeMe₃

Base Information

Chemical Name:(Z)-PhCHCHGeMe₃
CAS No.:31790-89-3
Molecular Formula:C₁₁H₁₆Ge
Molecular Weight:220.838
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-PhCHCHGeMe₃

Chemical Property:

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Technology Process of (Z)-PhCHCHGeMe₃

There total 2 articles about (Z)-PhCHCHGeMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 103-64-0,1340-14-3
bromostyrene

: 76054-64-3
7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-germanorbornadiene

: 14629-97-1
(E)-PhCHCHGeMe₃

: 31790-89-3
(Z)-PhCHCHGeMe₃

Guidance literature:: With CH₃MgBr; In diethyl ether; benzene; Norbornadiene-compound and PhCHCHBr are heated at 75°C for 4 h in benzene under Ar, methylation with MeMgBr in Et2O (first stirring at 0°C for 0.5 h, then at room temp. for 1 h).; a clear liquid are obtained by distillation (bp 60°C at 0.2 Torr) containing a mixture of PhCHCHBr, PhCHCHGeMe3, further insertion products are not found;

Reference yield:

: 622-25-3
1-(2-chlorovinyl)benzene

: 76054-64-3
7,7-dimethyl-1,4,5,6-tetraphenyl-2,3-benzo-7-germanorbornadiene

: 14629-97-1
(E)-PhCHCHGeMe₃

: 113352-24-2
PhCHCHGeMe₂GeMe₃

: 113352-25-3
PhCHCHGeMe₂GeMe₂GeMe₃

: 31790-89-3
(Z)-PhCHCHGeMe₃

Guidance literature:: With CH₃MgCl; In diethyl ether; benzene; Norbornadiene-compound and PhCHCHCl are heated at 75°C for 4 h in benzene under Ar, then methylation is following with MeMgCl in Et2O (stirring first at 0°C (0.5 h), then for 1 h at room temp.).; distillation gaves two fractions, first fraction (bp 60°C at 1 Torr) contains PhCHCHCl, PhCHCHGeMe3, second fraction (bp 180°C at 0.5 Torr) contains PhCHCHGeMe2GeMe3, PhCHCHGeMe2GeMe2GeMe3, all products are detected by GC-MS anal.;