D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate)

Base Information

Chemical Name:D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate)
CAS No.:103042-48-4
Molecular Formula:C₂₆H₃₀O₁₃S₂
Molecular Weight:614.648
Hs Code.:
European Community (EC) Number:600-384-5
DSSTox Substance ID:DTXSID701162985

Synonyms:DTXSID701162985;D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate);103042-48-4

Suppliers and Price of D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate)

Chemical Property:

Vapor Pressure:2.13E-20mmHg at 25°C
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:13
Rotatable Bond Count:13
Exact Mass:614.11278335
Heavy Atom Count:41
Complexity:1120

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2C(C(C(C(O2)OC(=O)C)OS(=O)(=O)C3=CC=C(C=C3)C)OC(=O)C)OC(=O)C
Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]2[C@H]([C@@H]([C@H](C(O2)OC(=O)C)OS(=O)(=O)C3=CC=C(C=C3)C)OC(=O)C)OC(=O)C

Technology Process of D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate)

There total 2 articles about D-Glucopyranose, 1,3,4-triacetate 2,6-bis(4-methylbenzenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-24-7
acetic anhydride

: 2,6-di-O-tosyl-glucopyranose

: 103042-48-4
3,4-di-O-acetyl-2,6-di-O-tosyl-α/β-D-glucopyranose

Guidance literature:: dmap; In dichloromethane; at 20 - 43 ℃; for 4.5h;

Reference yield:

: 108-24-7
acetic anhydride

: 6619-07-4,26391-80-0,121363-57-3,121363-64-2,121363-65-3,121363-70-0
6-O-toluolsulfonyl-D-glucopyranose

: 2,6-di-O-tosyl-glucopyranose

: 95118-61-9
1,2,3,4-tetra-O-acetyl-6-O-p-tolylsulfonyl-α,β-D-glucopyranose

: 103042-48-4
3,4-di-O-acetyl-2,6-di-O-tosyl-α/β-D-glucopyranose

Guidance literature:: With pyridine; for 24h; Yield given. Title compound not separated from byproducts; Ambient temperature;
DOI:10.1016/0008-6215(89)85126-2

Reference yield: 62.0%

: 103042-48-4
3,4-di-O-acetyl-2,6-di-O-tosyl-α/β-D-glucopyranose

: 3868-04-0
1,6:3,4-dianhydro-β-D-altropyranose

Guidance literature:: 3,4-di-O-acetyl-2,6-di-O-tosyl-α/β-D-glucopyranose; With aluminum oxide; at 110 ℃; for 0.1h; microwave irradiation;

With sodium methylate; In methanol; dichloromethane; for 12h;
DOI:10.1055/s-2003-39168