trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2]

Base Information

• Chemical Name: trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2]
• CAS No.: 1191251-43-0
• Molecular Formula: C₃₄H₂₆N₄O₄Ru
• Molecular Weight: 655.675
• Mol file: 1191251-43-0.mol

Synonyms:

Chemical Property of trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2]

There total 1 articles about trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

tris(8-quinolinolato-N(1),O(8))ruthenium(III) (97373-74-5,111321-91-6,82602-13-9) + p-methoxyphenylisonitrile (10349-38-9) → trans,trans,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2] (1191080-69-9,1191251-43-0) + cis,cis,trans-[Ru(8-quinolinolato)2(4-methoxyphenyl isocyanide)2]

Guidance literature:

With Zn#Hg; In ethanol; refluxed under Ar; cooled to room temp., filtered, evapd. (vac.), dissolved in CH2Cl2, chromd. (silica gel, CH2Cl2/acetone), dried (vac.), recrystd. (CH2Cl2/n-hexane); elem. anal.;

DOI:10.1021/om900253h

upstream raw materials:

tris(8-quinolinolato-N⁽¹⁾,O⁽⁸⁾)ruthenium(III)

p-methoxyphenylisonitrile