2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

Base Information

Chemical Name:2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene
CAS No.:1329611-71-3
Molecular Formula:C₆₈H₅₈N₆
Molecular Weight:959.249
Hs Code.:

Synonyms:

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Chemical Property of 2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

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Technology Process of 2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

There total 6 articles about 2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 1329611-66-6
4,9-[B(OH)2]2DHP

: 89972-76-9
4'-(4-bromo-phenyl)-[2,2';6',2'']terpyridine

: 1329611-71-3
2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In water; toluene; for 36h; Inert atmosphere; Reflux;
DOI:10.1021/ic2003904

Reference yield:

: 76626-75-0
2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

: 1329611-71-3
2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:: Multi-step reaction with 4 steps

1.1: N-Bromosuccinimide

2.1: n-butyllithium / diethyl ether; hexane / 1 h / -78 °C / Inert atmosphere

2.2: 48 h / 20 °C / Inert atmosphere

3.1: hydrogenchloride; water / diethyl ether; hexane / 3 h

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 36 h / Inert atmosphere; Reflux

With hydrogenchloride; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; sodium carbonate; In diethyl ether; hexane; water; toluene; 4.1: Suzuki coupling;
DOI:10.1021/ic2003904

Reference yield:

: 181486-12-4
4,9-dibromo-2,7-di-tert-butyl-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

: 1329611-71-3
2,7-di-tert-butyl-di((2,2’:6′,2″-terpyridin-yl)benzyl-4,9-yl)-trans-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / diethyl ether; hexane / 1 h / -78 °C / Inert atmosphere

1.2: 48 h / 20 °C / Inert atmosphere

2.1: hydrogenchloride; water / diethyl ether; hexane / 3 h

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; toluene / 36 h / Inert atmosphere; Reflux

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; water; sodium carbonate; In diethyl ether; hexane; water; toluene; 3.1: Suzuki coupling;
DOI:10.1021/ic2003904