(N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(diphenyl sulfide)

Base Information

• Chemical Name: (N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(diphenyl sulfide)
• CAS No.: 1000020-65-4
• Molecular Formula: C₃₈H₅₀NP₂RhS
• Molecular Weight: 717.741

Synonyms:

Chemical Property of (N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(diphenyl sulfide)

Chemical Property:

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Technology Process of (N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(diphenyl sulfide)

There total 5 articles about (N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(diphenyl sulfide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

(N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(Me)(Cl) (691894-30-1) + diphenyl sulfide (139-66-2) → (N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(diphenyl sulfide) (1000020-65-4)

Guidance literature:

With C₆H₅Li; In dibutyl ether; benzene-d6; (Ar); Rh complex treated with ligand in C6D6, C6H5Li in (C4H9)2O added, reacted at ambient temp.; evapd., chromd. (silica gel, Et2O), evapd., dissolved in Et2O, pptd. at -35°C;

DOI:10.1021/om700563k

Reference yield:

(N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(Me)(Cl) (691894-30-1) → (N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(SPh)(Ph) (1000020-74-5) + (N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(diphenyl sulfide) (1000020-65-4)

Guidance literature:

Multi-step reaction with 2 steps

1: CH₃MgCl / tetrahydrofuran; fluorobenzene

2: benzene-d6

With CH₃MgCl; In tetrahydrofuran; fluorobenzene; benzene-d6;

DOI:10.1021/om700563k

Reference yield:

(N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(SPh)(Ph) (1000020-74-5) → (N(C6H3(CH3)P(CH(CH3)2)2)2)Rh(diphenyl sulfide) (1000020-65-4)

Guidance literature:

In benzene-d6; (Ar); at 65°C for 18 h; not isolated, detected by NMR;

DOI:10.1021/om700563k

upstream raw materials:

(N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(Me)(Cl)

diphenyl sulfide

[Rh(bis(o-diisopropylphosphino-p-methylphenyl)amide)(diisopropylsulfide)]

(N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(SPh)(Ph)

Downstream raw materials:

(N(C₆H₃(CH₃)P(CH(CH₃)2)2)2)Rh(SPh)(Ph)

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