[Ir(III)(2-phenylpyridine)2(MeC₅H₃NNC₅H₃CH(SPh)CH₂C(O)C₆H₄NEt₂)](PF₆)

Base Information

• Chemical Name: [Ir(III)(2-phenylpyridine)2(MeC₅H₃NNC₅H₃CH(SPh)CH₂C(O)C₆H₄NEt₂)](PF₆)
• CAS No.: 1252795-71-3
• Molecular Formula: C₅₂H₄₇IrN₅OS*F₆P
• Molecular Weight: 1127.23
• Mol file: 1252795-71-3.mol

Synonyms:

Chemical Property of [Ir(III)(2-phenylpyridine)2(MeC₅H₃NNC₅H₃CH(SPh)CH₂C(O)C₆H₄NEt₂)](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(III)(2-phenylpyridine)2(MeC₅H₃NNC₅H₃CH(SPh)CH₂C(O)C₆H₄NEt₂)](PF₆)

There total 1 articles about [Ir(III)(2-phenylpyridine)2(MeC₅H₃NNC₅H₃CH(SPh)CH₂C(O)C₆H₄NEt₂)](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Ir(III)(2-phenylpyridine)2(MeC5H3NNC5H3CHCHC(O)C6H4NEt2)](PF6)*H2O + thiophenol (108-98-5) → [Ir(III)(2-phenylpyridine)2(MeC5H3NNC5H3CH(SPh)CH2C(O)C6H4NEt2)](PF6) (1252795-71-3)

Guidance literature:

With CH₃ONa; In methanol; dichloromethane; under Ar; mixt. of PhSH and MeONa in MeOH stirred at room temp. for 10 min; CH2Cl2 soln. of Ir complex added with stirring for 30 min; evapd. in vac.; dissolved in CH2Cl2; H2O added; org. layer collected; dried (MgSO4) overnight; purified by column chromy. (silica gel, CH2Cl2-acetone 50:1); elem. anal.;

DOI:10.1039/c0dt00456a

upstream raw materials:

thiophenol