(P(C₆H₅)3)2(CH₃COO)RhC₂B₉H₁₁

Base Information

• Chemical Name: (P(C₆H₅)3)2(CH₃COO)RhC₂B₉H₁₁
• CAS No.: 95858-33-6
• Molecular Formula: C₄₀H₄₄B₉O₂P₂Rh
• Molecular Weight: 818.94
• Mol file: 95858-33-6.mol

Synonyms:

Chemical Property of (P(C₆H₅)3)2(CH₃COO)RhC₂B₉H₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (P(C₆H₅)3)2(CH₃COO)RhC₂B₉H₁₁

There total 1 articles about (P(C₆H₅)3)2(CH₃COO)RhC₂B₉H₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Isopropenyl acetate (108-22-5) + closo-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11 (53687-46-0) → (P(C6H5)3)2(CH3COO)RhC2B9H11 (95858-33-6) + P(C6H5)3(CH3COO)RhC2B9H11 (95858-32-5)

Guidance literature:

In benzene; under argon, at 40°C for 3 days; addn. of heptane, reduction of volume in vac. led to pptn. of orange powder, repetead recrystn., elem. anal., when orange powder was fractionally recrystd. from benzene/heptane closo-3,3-(PPh3)2-3-(CH3COO)-3,1,2-RhC2B9H11 obtained;

DOI:10.1016/0022-328X(85)87009-1

Reference yield:

(P(C6H5)3)2(CH3COO)RhC2B9H11 (95858-33-6) → closo-3,3-(PPh3)2-3-H-3,1,2-RhC2B9H11 (53687-46-0)

Guidance literature:

With hydrogen; In not given;

DOI:10.1016/0022-328X(85)87009-1

Reference yield:

(P(C6H5)3)2(CH3COO)RhC2B9H11 (95858-33-6) → C38H40B9P2Rh

Guidance literature:

In not given; byproducts: CH3COOH; at 80°C;

DOI:10.1016/0022-328X(85)87009-1

upstream raw materials:

Isopropenyl acetate

closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

Downstream raw materials:

closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁