[(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf

Base Information

• Chemical Name: [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf
• CAS No.: 404579-24-4
• Molecular Formula: CF₃O₃S*C₄₃H₃₉O₂P₇ReS₃
• Molecular Weight: 1236.07
• Mol file: 404579-24-4.mol

Synonyms:

Chemical Property of [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf

There total 1 articles about [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phosphorus sulfide (1314-85-8) + [Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate (222402-52-0) → [(triphos)Re(CO)2(η1-P(apical)-P4S3]OTf + [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf (404579-24-4,404579-22-2)

Guidance literature:

In dichloromethane; CH2Cl2 soln. of Re-complex was treated under N2 at room temp. with soln.of P4S3 in CH2Cl2, stirred at room temp. for 1 h; concd. under vac., hexane was added, filtered under N2, washed with light petroleum ether, dried under N2; elem. anal.;

DOI:10.1021/ic010559f

Reference yield: 75.0%

[Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate (222402-52-0) + [(triphos)Re(CO)2(η1-P(apical)-P4S3]OTf + [(triphos)Re(CO)2(η1-P(basal)-P4S3]OTf (404579-24-4,404579-22-2) → [(triphos)Re(CO)2]2(μ,η1:1-P(apical),P(basal)-P4S3](OTf)2

Guidance literature:

In dichloromethane; soln. of Re-complexes was reacted in CH2Cl2, refluxed for 30 min; concd. under vac., hexane was added, filtered under N2, washed with light petroleum ether, dried under N2; elem. anal.;

DOI:10.1021/ic010559f

upstream raw materials:

phosphorus sulfide

[Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate