3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

Base Information

Chemical Name:3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde
CAS No.:915141-58-1
Molecular Formula:C₄₃H₇₂O₇Si₂
Molecular Weight:757.211
Hs Code.:

3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

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Chemical Property of 3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

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Technology Process of 3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

There total 3 articles about 3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 899828-02-5
3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propan-1-ol

: 915141-58-1
3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

Guidance literature:: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
DOI:10.1055/s-2006-949614

Reference yield:

: 915141-67-2
dithiocarbonic acid O-[1-[3-[6-(3-benzyloxy-propyl)-2-phenyl-[1,3]dioxan-4-yl]-2-(tert-butyl-dimethyl-silanyloxy)-propyl]-5-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-pentyl] ester S-methyl ester

: 915141-58-1
3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / AIBN; Bu₃SnH / toluene / Heating

2: 86 percent / H₂; Raney nickel

3: 93 percent / iodoxybenzoic acid

With 2,2'-azobis(isobutyronitrile); hydrogen; tri-n-butyl-tin hydride; nickel; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In toluene;
DOI:10.1055/s-2006-949614

Reference yield:

: 899827-96-4
(2S,4S,6S)-4-(3-Benzyloxy-propyl)-6-[(2S,5R,6S,7R)-2,8-bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxane

: 915141-58-1
3-{(2S,4S,6S)-6-[(2S,5R,6S,7R)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-6-(4-methoxy-benzyloxy)-5,7-dimethyl-octyl]-2-phenyl-[1,3]dioxan-4-yl}-propionaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / H₂; Raney nickel

2: 93 percent / iodoxybenzoic acid

With hydrogen; nickel; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione;
DOI:10.1055/s-2006-949614