((triphos)Rh(μ-S)2Co(triphos))(BPh4)2

Base Information

Chemical Name:((triphos)Rh(μ-S)2Co(triphos))(BPh4)2
CAS No.:113686-46-7
Molecular Formula:2C₂₄H₂₀B*C₈₂H₇₈CoP₆RhS₂
Molecular Weight:2113.86
Hs Code.:

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Chemical Property of ((triphos)Rh(μ-S)2Co(triphos))(BPh4)2

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Technology Process of ((triphos)Rh(μ-S)2Co(triphos))(BPh4)2

There total 1 articles about ((triphos)Rh(μ-S)2Co(triphos))(BPh4)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 99955-64-3
((triphos)Rh(S₂CO))BPh₄

: 143-66-8
sodium tetraphenyl borate

: cobalt(II) perchlorate hexahydrate

: 22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

: 113686-46-7
((triphos)Rh(μ-S)2Co(triphos))(BPh4)2

Guidance literature:: In ethanol; dichloromethane; butan-1-ol; byproducts: carbon monoxide; n-butanol soln. of Co(ClO4)2*6H2O heated at boiling temp., addn. of triphos in CH2Cl2 and then ((triphos)Rh(S2CO))BPh4 in CH2Cl2, addn. of NaBPh4 in ethanol; evapn. of solvent; elem. anal.;
DOI:10.1021/ja00220a032

Reference yield: 35.0%

: 16940-66-2
sodium tetrahydroborate

: 113686-46-7
((triphos)Rh(μ-S)2Co(triphos))(BPh4)2

: 113686-52-5
((triphos)Rh(μ-S)2Co(triphos))BPh4

Guidance literature:: In ethanol; dichloromethane; dropwise addn. of NaBH4 in ethanol to a soln. of ((CH3C(CH2PPh2)3)Rh(S)2Co(CH3C(CH2PPh2)3))(BPh4)2 in CH2Cl2; addn. of ethanol, partial evapn. of solvent under a fast stream of nitrogen; elem. anal.;
DOI:10.1021/ja00220a032