10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene-9-carboxylic acid methyl ester

Base Information

• Chemical Name: 10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene-9-carboxylic acid methyl ester
• CAS No.: 66741-04-6
• Molecular Formula: C₂₈H₂₈O₄S
• Molecular Weight: 460.594
• Mol file: 66741-04-6.mol

Synonyms:

Chemical Property of 10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene-9-carboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene-9-carboxylic acid methyl ester

There total 2 articles about 10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.0^2,7]undeca-2⁽⁷⁾,3,5-triene-9-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1,3-diphenylisobenzofuran (5471-63-6) + Methyl trans-(tert-butylsulfinyl)acrylate (66713-31-3) → 10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-9-carboxylic acid methyl ester (66741-04-6)

Guidance literature:

In benzene; for 4h; Heating;

DOI:10.1021/jo00330a017

Reference yield:

→ (R)-10-(2-Methyl-propane-2-sulfinyl)-1,8-diphenyl-11-oxa-tricyclo[6.2.1.02,7]undeca-2(7),3,5-triene-9-carboxylic acid methyl ester (66741-04-6)

Guidance literature:

aus entspr. Sulfoxid 4a, 1,3-Diphenylisobenzofuran;

DOI:10.1016/S0040-4039(01)85053-X

upstream raw materials:

1,3-diphenylisobenzofuran

Methyl trans-(tert-butylsulfinyl)acrylate