trans-(triphenylphosphane)2PtH(SnCl₃)

Base Information

• Chemical Name: trans-(triphenylphosphane)2PtH(SnCl₃)
• CAS No.: 18117-31-2
• Molecular Formula: C₃₆H₃₁Cl₃P₂PtSn
• Molecular Weight: 945.739
• Mol file: 18117-31-2.mol

Synonyms:

Chemical Property of trans-(triphenylphosphane)2PtH(SnCl₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-(triphenylphosphane)2PtH(SnCl₃)

There total 19 articles about trans-(triphenylphosphane)2PtH(SnCl₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

PtCl(COC6H13)(P(C6H5)3)2 + tin(ll) chloride → heptanal (111-71-7) + trans-(triphenylphosphane)2PtH(SnCl3) (18117-31-2,82509-99-7,16902-94-6)

Guidance literature:

With hydrogen; In dichloromethane-d2; a soln. of Pt-complex and SnCl2 was kept under H2 overnight; a minor amt. of other hydrido species was formed (NMR); addn. of ethanol to the reaction mixt. resulted in the absence of the reaction; (1)H and (31)P NMR data;

DOI:10.1016/0022-328X(85)87240-5

Reference yield:

trans-chlorohydridobis(triphenylphosphine)platinum(II) (16841-99-9,25879-12-3,16902-93-5) → trans-(triphenylphosphane)2PtH(SnCl3) (18117-31-2,82509-99-7,16902-94-6)

Guidance literature:

Multi-step reaction with 3 steps

1: triphenyl phosphine; CO / ethanol

2: CHCl₃ / chloroform

With triphenyl phosphine; CO; CHCl₃; In ethanol; chloroform;

DOI:10.1021/om00058a019

Reference yield:

trans-{PtCl(COC5H11)(PPh3)2} (136764-71-1) → trans-(triphenylphosphane)2PtH(SnCl3) (18117-31-2,82509-99-7,16902-94-6)

Guidance literature:

Multi-step reaction with 2 steps

1: CHCl₃ / chloroform

With CHCl₃; In chloroform;

DOI:10.1021/om00058a019

upstream raw materials:

trans-chlorohydridobis(triphenylphosphine)platinum(II)

{PtH(SnCl₃)(CO)(PPh₃)2}

PtH(CO)(P(C₆H₅)3)2⁽¹⁺⁾*SnCl₃^(1-) = PtH(CO)(P(C₆H₅)3)2SnCl₃

trans-{Pt(SnCl₃)(COC₅H₁₁)(PPh₃)2}

Downstream raw materials:

trans-{Pt(SnCl₃)(C₅H₁₁)(PPh₃)2}

(triphenylphosphino)3platinum(II)hydride⁽¹⁺⁾

cis-dichlorobis(triphenylphosphine)platinum(II)

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]