HNb(CO)3(P(CH₂CH₂P(C₆H₅)2)3)

Base Information

• Chemical Name: HNb(CO)3(P(CH₂CH₂P(C₆H₅)2)3)
• CAS No.: 93799-65-6
• Molecular Formula: C₄₅H₄₃NbO₃P₄
• Molecular Weight: 848.636
• Mol file: 93799-65-6.mol

Synonyms:

Chemical Property of HNb(CO)3(P(CH₂CH₂P(C₆H₅)2)3)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of HNb(CO)3(P(CH₂CH₂P(C₆H₅)2)3)

There total 1 articles about HNb(CO)3(P(CH₂CH₂P(C₆H₅)2)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.5%

cis-[Et4N][Nb(CO)4(P(CH2CH2PPh2)3)] (93824-03-4) → HNb(CO)3(P(CH2CH2P(C6H5)2)3) (93799-65-6)

Guidance literature:

With silica gel; In tetrahydrofuran; (N2); complex soln. transferred to silica gel column, eluted with THF; evapd., oil washed with pentane, solidified under vac.; elem. anal.;

DOI:10.1016/0022-328X(84)80629-4

Reference yield:

HNb(CO)3(P(CH2CH2P(C6H5)2)3) (93799-65-6) → HNb(CO)2(P(CH2CH2P(C6H5)2)3) (108443-51-2)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); (N2 or Ar); Hg lamp; internal irradiation (30 min); pentane added, recrystd. (THF/pentane);

DOI:10.1016/S0022-328X(00)99517-2

upstream raw materials:

cis-[Et₄N][Nb(CO)4(P(CH₂CH₂PPh₂)3)]

Downstream raw materials:

HNb(CO)2(P(CH₂CH₂P(C₆H₅)2)3)