bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate

Base Information

• Chemical Name: bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate
• CAS No.: 347148-48-5
• Molecular Formula: C₃₅H₅₉InN₄
• Molecular Weight: 650.7
• Mol file: 347148-48-5.mol

Synonyms:

Chemical Property of bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate

There total 2 articles about bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.3%

dichloroindium tert-butyl-N,N'-diisopropylamidinate (347148-47-4) + lithium (2,6-diisopropylphenyl)amide → bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate (347148-48-5)

Guidance literature:

In diethyl ether; under dry N2 using high-vac. techniques; Li salt in Et2O added to In-complex in Et2O at 0°C; stirred overnight at room temp.; volatiles removed (vac.); residue extd. (hexane) and filtered; filtrate concd. and cooled to -10°C overnight; elem. anal.;

DOI:10.1021/om020021x

Reference yield:

lithium N,N′-diisopropyl-2-tert-butyl-amidinate → bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate (347148-48-5)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: diethyl ether

In diethyl ether;

DOI:10.1021/om020021x

Reference yield: 32.6%

tetrakis(dimethylamido)titanium(IV) + bis(2,6-diisopropylaniline)indium tert-butyl-N,N'-diisopropylamidinate (347148-48-5) → bis(dimethylamido)bis(2,6-diisopropylaniline)indium (tert-butyl-N,N'-diisopropylamidinate)titanium

Guidance literature:

In benzene; under dry N2 using high-vac. techniques; mixt. heated in benzene at 60°C for 8 h under N2 bubbler; volatiles removed (vac.); residue extd. (toluene) and filtered; filtrateconcd.; cooled to -10°C overnight;

DOI:10.1021/om020021x

upstream raw materials:

dichloroindium tert-butyl-N,N'-diisopropylamidinate