Technology Process of (Methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)phenylmethane
There total 8 articles about (Methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)phenylmethane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
2-Methyl-2-nitropropane; boron trifluoride diethyl etherate; hypophosphorous acid;
In
dichloromethane;
1.) -78 deg C, 30 min, 2.) r.t., overnight;
DOI:10.1080/07328309608005690
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 50 percent / TMSI / CH2Cl2 / 0.5 h / Ambient temperature
2: TEMPO, NaOCl, KBr, aq. NaHCO3 / 1.5 h
3: dimethylformamide / 24 h / Ambient temperature
4: DMAP / dimethylformamide / 24 h / Ambient temperature
With
dmap; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; trimethylsilyl iodide; sodium hydrogencarbonate; potassium bromide;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1080/07328309608005690
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) Mg / 2.) ether, reflux, 4 h
2: H2 / 10percent Pd-C / acetic acid / 19 h / 2068.6 Torr
3: O2 / PtO2 / H2O
4: 1percent H2SO4 / Heating
5: pyridine
With
pyridine; sulfuric acid; hydrogen; oxygen; magnesium;
platinum(IV) oxide; palladium on activated charcoal;
In
water; acetic acid;