DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

Base Information

Chemical Name:DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate
CAS No.:121916-57-2
Molecular Formula:C₈H₁₈N₂O₃*H₂O₄S
Molecular Weight:288.322
Hs Code.:

Synonyms:

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Chemical Property of DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

Chemical Property:

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Technology Process of DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

There total 4 articles about DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 87902-30-5,121916-52-7
DL-(1α,2α,3β,4β,5α)-1,2-anhydro-3-O,4-N-carbonyl-5-O-methyl-4-(methylamino)-1,2,3,5-cyclohexanetetrol

: 121916-57-2
DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / KI / acetic acid / 2.5 h / Ambient temperature

2: 93 percent / hexamethylguanidinium azide / acetonitrile / 4 h / 40 °C

3: 98 percent / H₂ / Pd/C / methanol / 12 h / Ambient temperature

4: 1) Ba(OH)2*8H₂O, 2) conc. H₂SO₄ / 1) H₂O/CH₃OH, reflux, 4 h, 2) H₂O/CH₃OH

With barium dihydroxide; hexamethylguanidinium azide; sulfuric acid; hydrogen; potassium iodide; palladium on activated charcoal; In methanol; acetic acid; acetonitrile;

Reference yield:

: 121811-38-9
DL-(1α,2β,3β,4α,6β)-2-O,3-N-carbonyl-6-iodo-4-O-methyl-3-(methylamino)-1,2,4-cyclohexanetriol

: 121916-57-2
DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / hexamethylguanidinium azide / acetonitrile / 4 h / 40 °C

2: 98 percent / H₂ / Pd/C / methanol / 12 h / Ambient temperature

3: 1) Ba(OH)2*8H₂O, 2) conc. H₂SO₄ / 1) H₂O/CH₃OH, reflux, 4 h, 2) H₂O/CH₃OH

With barium dihydroxide; hexamethylguanidinium azide; sulfuric acid; hydrogen; palladium on activated charcoal; In methanol; acetonitrile;

Reference yield:

: 121811-39-0
DL-(1α,2β,3β,4α,6β)-1-O-acetyl-2-O,3-N-carbonyl-6-iodo-4-O-methyl-3-(methylamino)-1,2,4-cyclohexanetriol

: 121916-57-2
DL-(1α,2β,3β,4α,6α)-6-ammonio-4-O-methyl-3-(methylammonio)-1,2,4-cyclohexanetriol sulfate

Guidance literature:: Multi-step reaction with 5 steps

1: 20 percent / 2-(tert-butylimino)-2-(diethylamino)hexahydro-1,3-dimethyl-1,3,2λ⁵-diazaphosphorine / acetonitrile / 48 h / Ambient temperature

2: 97 percent / KI / acetic acid / 2.5 h / Ambient temperature

3: 93 percent / hexamethylguanidinium azide / acetonitrile / 4 h / 40 °C

4: 98 percent / H₂ / Pd/C / methanol / 12 h / Ambient temperature

5: 1) Ba(OH)2*8H₂O, 2) conc. H₂SO₄ / 1) H₂O/CH₃OH, reflux, 4 h, 2) H₂O/CH₃OH

With barium dihydroxide; hexamethylguanidinium azide; sulfuric acid; hydrogen; 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine; potassium iodide; palladium on activated charcoal; In methanol; acetic acid; acetonitrile;