9,10-Anthracenedione, 2-iodo-

Base Information

• Chemical Name: 9,10-Anthracenedione, 2-iodo-
• CAS No.: 10566-32-2
• Molecular Formula: C14H7IO2
• Molecular Weight: 334.113
• DSSTox Substance ID: DTXSID60407470
• Nikkaji Number: J2.565.909K
• Wikidata: Q82212736
• Mol file: 10566-32-2.mol

Synonyms:9,10-Anthracenedione, 2-iodo-;2-iodoanthracene-9,10-dione;10566-32-2;ss-Jodanthrachinon;2- Jod-anthrachinon;SCHEMBL6449287;DTXSID60407470;AKOS001588353;EU-0000277;2-IODO-9,10-DIHYDROANTHRACENE-9,10-DIONE;InChI=1/C14H7IO2/c15-8-5-6-11-12(7-8)14(17)10-4-2-1-3-9(10)13(11)16/h1-7

Chemical Property of 9,10-Anthracenedione, 2-iodo-

Chemical Property:

• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 333.94908
• Heavy Atom Count: 17
• Complexity: 352

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C(=O)C3=C(C2=O)C=C(C=C3)I

Technology Process of 9,10-Anthracenedione, 2-iodo-

There total 1 articles about 9,10-Anthracenedione, 2-iodo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

anthracen-9(10H)-one (90-44-8) → 2-iodo-anthraquinone (10566-32-2) + 9,10-phenanthrenequinone (84-65-1)

Guidance literature:

With iodine tris(trifluoroacetate); In dichloromethane; for 6h; Ambient temperature;

DOI:10.1246/bcsj.60.4363

Reference yield: 97.0%

2-iodo-anthraquinone (10566-32-2) + 4-ethynyl-N,N-dimethylaniline (17573-94-3,752235-18-0) → 2-{[4-(dimethylamino)phenyl]ethynyl}anthracene-9,10-dione (1032401-47-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; at 20 ℃; for 0.0833333h;

DOI:10.1002/ejoc.200700970

Reference yield: 96.0%

2-iodo-anthraquinone (10566-32-2) + 4-(dimethylamino)benzene-boronic acid (28611-39-4) → 2-[4-(dimethylamino)phenyl]anthracene-9,10-dione (1032401-46-9)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate; In tetrahydrofuran; water; at 60 ℃; for 1h;

DOI:10.1002/ejoc.200700970

upstream raw materials:

anthracen-9(10H)-one

Downstream raw materials:

[2,2']bianthryl-9,10,9',10'-tetraone

N-(2-Anthraquinonyl)-p-methylbenzenesulfonamide

nitrobenzene

2-(2-nitro-anilino)-anthraquinone