(tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C₆F₅)₂]

Base Information

• Chemical Name: (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C₆F₅)₂]
• CAS No.: 741272-50-4
• Molecular Formula: C₁₆H₃₆N*C₂₅H₈F₁₀NPt
• Molecular Weight: 949.878
• Mol file: 741272-50-4.mol

Synonyms:

Chemical Property of (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C₆F₅)₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C₆F₅)₂]

There total 1 articles about (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C₆F₅)₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

[NBu4][Pt(C6F5)3(7,8-benzo[h]quinoline)] (181645-31-8) → (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C6F5)2] (741272-50-4)

Guidance literature:

In 1,2-dichloro-ethane; soln. (Bu4N)(Pt(C6F5)3(7,8-benzoquinoline)) in ClCH2CH2Cl was refluxed for 3 h and allowed to cool to room temp.; soln. was evapd. to dryness, residue was treated with i-PrOH, filtered off, washed with n-hexane, and vac.-dried; elem. anal.;

DOI:10.1021/om049719w

Reference yield: 77.0%

perchlorato(triphenylphosphane)silver(I) (73165-02-3,623171-38-0) + (tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C6F5)2] (741272-50-4) → [(Pt(7,8-benzoquinolate)(C6F5)2)Ag(PPh3)]

Guidance literature:

In dichloromethane; byproducts: Bu4NClO4; Ag compd. (1 equiv.) was added to soln. of Pt complex (1 equiv.) in CH2Cl2; stirred for 1 h in absence of light; evapd.; treated with Et2O; filtered; filtrate evapd.; residue treated with hexane; filtered; air-dried; elem. anal.;

DOI:10.1021/om0604526

Reference yield: 76.0%

(tetrabutylammonium)[Pt(7,8-benzoquinolinyl)(C6F5)2] (741272-50-4) + silver perchlorate → [PtAg(7,8-benzoquinolate)(C6F5)2]

Guidance literature:

In acetone; to soln. of AgClO4 in acetone, Pt complex added; stirred for 1 h in absence of light; evapd. to dryness; CH2Cl2 added; ppt. filtered off, washed with cold CH2Cl2, vac. dried; elem. anal.;

DOI:10.1039/c2dt11885h

upstream raw materials:

[NBu₄][Pt(C₆F₅)3(7,8-benzo[h]quinoline)]

Downstream raw materials:

[(C₆F₅)2(7,8-benzoquinolinate)PtCd(1,4,7,10-tetraazacyclododecane)](ClO₄)

Pt(7,8-benzoquinolate)(C₆F₅)(pyridine)