Technology Process of [RuH(P(OEt)3)5][BPh4]
There total 1 articles about [RuH(P(OEt)3)5][BPh4] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
HBF4*Et2O;
In
ethanol;
under an inert atm.; phosphite (0.56 mmol) was added to a soln. of Ru-contg. compd. (0.56 mmol) in ethanol; cooling to -196°C; HBF4*Et2O (0.57 mol) was added; stirring for ca. 2 h at room temp.; addn. of an excess of NaBPh4 (1.2 mmol); the solid was filtered and crystd. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1039/b202888n
- Guidance literature:
-
In
acetone;
under an inert atm.; Os-contg. compd. (0.1 mmol) and (PhN2)BF4 (0.5 mmol) were placed in the flask; cooling to -196°C; acetone was slowlyadded; stirring at room temp. for 4 h; the solvent was removed under reduced pressure; the oil was treated withethanol contg. an excess of NaBPh4 (0.2 mmol); the solid was slowly sep d. out, then filtered and crystd. from CH2Cl2 and ethanol; elem. anal.;
DOI:10.1039/b202888n
- Guidance literature:
-
With
HBF4*Et2O;
In
dichloromethane;
byproducts: H2; under an inert atm.; HBF4*Et2O (0.4 mmol) was added to a soln. of Ru-contg. compd. (0.1 mmol) in CH2Cl2; cooling to ca. -196°C; under H2 atm; stirring for 2 h at room temp.; under Ar; NH2NH2 (1 mmol) was added; stirring for 20 h; the solvent was removed under reduced pressure; the oil was triturated with ethanol contg. an excess of NaBPh4 (0.2 mmol); the solid was filtered and crystd. from CH2Cl2 and ethanol; elem. anal.;
DOI:10.1039/b202888n
