Me2Al(μ-OSiMe2C(CH3)3)2AlMe2

Base Information

• Chemical Name: Me2Al(μ-OSiMe2C(CH3)3)2AlMe2
• CAS No.: 511512-66-6
• Molecular Formula: C₁₆H₄₂Al₂O₂Si₂
• Molecular Weight: 376.642
• Mol file: 511512-66-6.mol

Synonyms:

Chemical Property of Me2Al(μ-OSiMe2C(CH3)3)2AlMe2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Me2Al(μ-OSiMe2C(CH3)3)2AlMe2

There total 1 articles about Me2Al(μ-OSiMe2C(CH3)3)2AlMe2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(cyclopentadienyl)dimethylzirconium(IV) (12636-72-5) + (Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4) (511512-70-2) → Me2Al(μ-OSiMe2C(CH3)3)2AlMe2 (511512-66-6) + [Cp2ZrCH2NMePh][B(C6F5)4] (511512-82-6)

Guidance literature:

In benzene-d6; byproducts: CH4; (Ar); using Schlenk techniques; sealing of NMR tube with stock soln. of (((t-Bu)Me2SiO)2Al2Me3NMe2Ph)(B(C6F5)4) and Cp2ZrMe2 in C6D6 at room temp.; keeping at -80°C until the first meausurement; heating to 300K; monitoring by NMR;

DOI:10.1021/om0207515

Reference yield: 88.0%

Me2Al(μ-OSiMe2C(CH3)3)2AlMe2 (511512-66-6) + N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate → (Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4) (511512-70-2)

Guidance literature:

In benzene-d6; byproducts: CH4; (Ar); using Schlenk techniques; treatment of (Me2NHPh)(B(C6F5)4) (1 equiv.) with ((t-Bu)Me2SiOAlMe2)2 in C6D6 at 75°C for 75 h;

DOI:10.1021/om0207515

upstream raw materials:

bis(cyclopentadienyl)dimethylzirconium(IV)

(Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4)

Downstream raw materials:

(Me2Al(μ-OSiMe2C(CH3)3)2AlMeNMe2Ph)(B(C6F5)4)