C₄₂H₅₄O₅S₂Si

Base Information

Chemical Name:C₄₂H₅₄O₅S₂Si
CAS No.:1392308-86-9
Molecular Formula:C₄₂H₅₄O₅S₂Si
Molecular Weight:731.105
Hs Code.:

C<sub>42</sub>H<sub>54</sub>O<sub>5</sub>S<sub>2</sub>Si

Synonyms:

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Chemical Property of C₄₂H₅₄O₅S₂Si

Chemical Property:

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Technology Process of C₄₂H₅₄O₅S₂Si

There total 16 articles about C₄₂H₅₄O₅S₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1392308-67-6
C₄₂H₅₄O₅S₂Si

: 1392308-66-5
C₄₂H₅₄O₅S₂Si

: 1392308-86-9
C₄₂H₅₄O₅S₂Si

Guidance literature:: With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; benzyl alcohol; In toluene; at 0 - 4 ℃; for 10h; optical yield given as %de;
DOI:10.1002/anie.201201653

Reference yield:

: 1392308-68-7
C₃₀H₃₇IO₃Si

: 1392308-66-5
C₄₂H₅₄O₅S₂Si

: 1392308-86-9
C₄₂H₅₄O₅S₂Si

Guidance literature:: Multi-step reaction with 4 steps

1.1: tert.-butyl lithium / diethyl ether; pentane / 1 h / -78 °C

1.2: 1 h / -78 - 0 °C

2.1: pyridinium p-toluenesulfonate / ethanol / 9 h / 25 °C

3.1: manganese(IV) oxide / dichloromethane / 0.33 h / 25 °C

4.1: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; benzyl alcohol / toluene / 10 h / 0 - 4 °C

With manganese(IV) oxide; (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; tert.-butyl lithium; pyridinium p-toluenesulfonate; benzyl alcohol; In diethyl ether; ethanol; dichloromethane; toluene; pentane;
DOI:10.1002/anie.201201653

Reference yield:

: 14947-48-9
2-(2'-hydroxyethyl)-1,3-dithiane

: 1392308-66-5
C₄₂H₅₄O₅S₂Si

: 1392308-86-9
C₄₂H₅₄O₅S₂Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: (+)-10-camphorsulfonic acid / dichloromethane / 1 h / 0 °C

2.1: n-butyllithium; dibutylmagnesium / tetrahydrofuran; hexane; n-heptane / 1 h / 25 °C

2.2: 1.5 h / -78 - 0 °C

3.1: zinc(II) chloride / diethyl ether; dichloromethane / 3 h / 25 °C

4.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine / dichloromethane / 1 h / 0 °C

5.1: tert.-butyl lithium / diethyl ether; pentane / 1 h / -78 °C

5.2: 1 h / -78 - 0 °C

6.1: pyridinium p-toluenesulfonate / ethanol / 9 h / 25 °C

7.1: manganese(IV) oxide / dichloromethane / 0.33 h / 25 °C

8.1: (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; benzyl alcohol / toluene / 10 h / 0 - 4 °C

With manganese(IV) oxide; n-butyllithium; (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; dibutylmagnesium; tert.-butyl lithium; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; dimethyl sulfoxide; (+)-10-camphorsulfonic acid; N-ethyl-N,N-diisopropylamine; zinc(II) chloride; benzyl alcohol; In tetrahydrofuran; diethyl ether; ethanol; hexane; n-heptane; dichloromethane; toluene; pentane; 4.1: Parikh-Doering oxidation;
DOI:10.1002/anie.201201653