μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

Base Information

Chemical Name:μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum
CAS No.:121289-47-2
Molecular Formula:C₅₄H₄₄As₂ClMoO₄P₂Rh
Molecular Weight:1203.03
Hs Code.:

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Chemical Property of μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

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Technology Process of μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

There total 2 articles about μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 14523-22-9
Rh(CO)4Cl₂

: 121289-43-8
fac-tricarbonylbis{((diphenylarsino)methyl)diphenylphosphane}molydenum

: 121289-47-2
μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

Guidance literature:: In dichloromethane; Rh(CO)4Cl2 reacts in CH2Cl2 with (CO)3Mo(Ph2AsCH2AsPh2)Ph2PCH2PPh2 at -10°C (0.5 h); product is filtered, washed with hexane and dried in vacuo, elem. anal.;

Reference yield:

: 121314-08-7
μ-{bis(diphenylarsino)methane}-μ-{bis(diphenylphosphino)methane}-μ-carbonyldicarbonyl(chlororhodium)-μ-(sulfur dioxide)molybdenum

: 121289-47-2
μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

Guidance literature:: With carbon monoxide; In not given; by reaction of CO with Mo(CO)3(SO2)(Ph2PCH2PPh2)(Ph2AsCH2AsPh2)RhCl (in soln.) the Mo(CO)4(Ph2PCH2PPh2)(Ph2AsCH2AsPh2)RhCl is formed;

Reference yield: 62.0%

: 121289-47-2
μ-{bis(diphenylarsino)methane}-μ-{(diphenylphosphino)methane}-di-μ-carbonyldicarbonyl(chlororhodium)molybdenum

: 121314-08-7
μ-{bis(diphenylarsino)methane}-μ-{bis(diphenylphosphino)methane}-μ-carbonyldicarbonyl(chlororhodium)-μ-(sulfur dioxide)molybdenum

Guidance literature:: With sulfur dioxide; In dichloromethane; byproducts: CO; a soln. of Mo(CO)4(Ph2PCH2PPh2)Ph2AsCH2AsPh2ReCl in CH2Cl2 is saturated with SO2 at 20°C, solvent and SO2 are removed, Mo(CO)3(SO2)(Ph2PCH2PPh2)Ph2AsCH2AsPh2ReCl is obtained; precipitate is recrystallized from CH2Cl2/acetone, elem. anal.;