PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

Base Information

Chemical Name:PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆
CAS No.:85944-39-4
Molecular Formula:C₅₄H₄₆P₃Pt*F₆P
Molecular Weight:1127.92
Hs Code.:

PtH(P(C<sub>6</sub>H<sub>5</sub>)3)3<sup>(1+)</sup>*PF<sub>6</sub><sup>(1-)</sup>={PtH(P(C<sub>6</sub>H<sub>5</sub>)3)3}PF<sub>6</sub>

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Chemical Property of PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

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Technology Process of PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

There total 4 articles about PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: ammonium hexafluorophosphate

: 13517-35-6
tris(triphenylphosphine)platinum⁽⁰⁾

: 85944-39-4
PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

Guidance literature:: In tetrahydrofuran; stirring of starting compounds in THF under Ar at 25°C for 48 h, then at 40°C for 12 h; all under Ar: solvent removing, dissolving in CH2Cl2, filtration (Florisil), diluting with pentane, cooling, elem. anal.; or addn. of pentane to reaction mixture, filtration, washing with pentane and benzene, extn. with CH2Cl2, NMR anal.;
DOI:10.1016/S0022-328X(00)98622-4

Reference yield: 88.0%

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: {W(C₅H₅)(CO)3((C₆H₅)2PH)}⁽¹⁺⁾*PF₆^(1-)={W(C₅H₅)(CO)3((C₆H₅)2PH)}PF₆

: {(η5-Cp)(CO)2W(μ-PPh2)Pt(CO))PPh3)}

: 85944-39-4
PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

Guidance literature:: In dichloromethane; react. under dry N2, dissolving Pt(C2H4)(PPh3)2 in CH2Cl2, dissolving (W(cp)(CO)3(PPh2H))PF6 in CH2Cl2, slow, dropwise addn. of this soln. to the Pt soln., 2:1 stoich., stirring for 30 min at 20°C; monitoring by IR spectroscopy, evapgn. in vac., extg. with hot, dry benzene, pptg. of (PtH(PPh3)3)PF6, removing the solvent from the mother liquor, recrystn. from a min. amt. of acetone, elem. anal.;
DOI:10.1039/DT9920002793

Reference yield: 79.0%

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: {Mo(C₅H₅)(CO)3((C₆H₅)2PH)}⁽¹⁺⁾*PF₆^(1-)={Mo(C₅H₅)(CO)3((C₆H₅)2PH)}PF₆

: 85944-39-4
PtH(P(C₆H₅)3)3⁽¹⁺⁾*PF₆^(1-)={PtH(P(C₆H₅)3)3}PF₆

: {Mo(C₅H₅)(CO)2((C₆H₅)2P)Pt(CO)(P(C₆H₅)3)}

Guidance literature:: In dichloromethane; react. under dry N2, dissolving Pt(C2H4)(PPh3)2 in CH2Cl2, dissolving (Mo(cp)(CO)3(PPh2H))PF6 in CH2Cl2, slow, dropwise addn. of this soln. to the Pt soln., 2:1 stoich., stirring for 30 min at 20°C; monitoring by IR spectroscopy, evapgn. in vac., extg. with hot, dry benzene, pptg. of (PtH(PPh3)3)PF6, removing the solvent from the mother liquor, recrystn. from a min. amt. of acetone, elem. anal.;
DOI:10.1039/DT9920002793