(Ru(CO)Cl(P(C₆H₅)3)2(C₉NH₆O))

Base Information

• Chemical Name: (Ru(CO)Cl(P(C₆H₅)3)2(C₉NH₆O))
• CAS No.: 93442-82-1
• Molecular Formula: C₄₆H₃₆ClNO₂P₂Ru
• Molecular Weight: 833.268
• Mol file: 93442-82-1.mol

Synonyms:

Chemical Property of (Ru(CO)Cl(P(C₆H₅)3)2(C₉NH₆O))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Ru(CO)Cl(P(C₆H₅)3)2(C₉NH₆O))

There total 1 articles about (Ru(CO)Cl(P(C₆H₅)3)2(C₉NH₆O)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

8-quinolinol (148-24-3,24804-14-6) + (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) → 8-hydroxyquinolato carbonyl chlorobis(triphenylphosphine)ruthenium(II) (93442-82-1,99295-73-5)

Guidance literature:

In 2-methoxy-ethanol; byproducts: H2, PPh3; The mixt. of reagents in 2-methoxyethanol was refluxed for 30 min, cooled to room temp.;; crystals were sepd., washed with hot hexane and dried in vac.; recrystd. from benzene and hexane; elem. anal.;;

Reference yield: 58.0%

(Ru(CO)Cl(P(C6H5)3)2(C9NH6O)) (93442-82-1,99295-73-5) + silver perchlorate + acrylonitrile (107-13-1,25014-41-9) → [(acrylonitrile)(quinoline-8-olato)carbonylbis(triphenylphosphine)ruthenium(II)] perchlorate (99252-08-1)

Guidance literature:

In further solvent(s); byproducts: AgCl; (under N2); addn. of AgClO4 to a soln. of the starting complex in acrylonitrile with stirring, stirring for 3 h; filtn. of AgCl, filtrate is concd. in vac., solid is washed (light petroleum), elem. anal.;

Reference yield: 50.0%

(Ru(CO)Cl(P(C6H5)3)2(C9NH6O)) (93442-82-1,99295-73-5) + silver perchlorate → [(acetonitrile)(quinoline-8-olato)carbonylbis(triphenylphosphine)ruthenium(II)] perchlorate (99252-04-7)

Guidance literature:

With CH₃CN; In acetonitrile; byproducts: AgCl; (under N2); addn. of AgClO4 to a soln. of the starting complex in acetonitrile with stirring, stirring for 3 h; filtn. of AgCl, filtrate is concd. in vac., solid is washed (light petroleum), elem. anal.;

upstream raw materials:

8-quinolinol

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

[(acetonitrile)(quinoline-8-olato)carbonylbis(triphenylphosphine)ruthenium(II)] perchlorate

[(acrylonitrile)(quinoline-8-olato)carbonylbis(triphenylphosphine)ruthenium(II)] perchlorate