1,3,5-tri-O-allyl-scyllo-inositol

Base Information

• Chemical Name: 1,3,5-tri-O-allyl-scyllo-inositol
• CAS No.: 865837-93-0
• Molecular Formula: C₁₅H₂₄O₆
• Molecular Weight: 300.352
• Mol file: 865837-93-0.mol

Synonyms:

Chemical Property of 1,3,5-tri-O-allyl-scyllo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,5-tri-O-allyl-scyllo-inositol

There total 3 articles about 1,3,5-tri-O-allyl-scyllo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S,5S,7R,8S,9R)-8,9-Bis-allyloxy-2,4,10-trioxa-tricyclo[3.3.1.13,7]decan-6-one → 1,3,5-tri-O-allyl-scyllo-inositol (865837-93-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 100 percent / NaBH₄ / methanol; tetrahydrofuran / 1 h / 20 °C

2.1: sodium hydride / tetrahydrofuran / 0.33 h / 0 °C

2.2: dimethylformamide / 2 h / 20 °C

3.1: 100 percent / p-toluene sulfonic acid / methanol; ethyl acetate / 1 h / 20 °C

With sodium tetrahydroborate; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethyl acetate;

DOI:10.1016/j.tetlet.2005.07.001

Reference yield:

4,6-di-O-allyl-scyllo-inositol 1,3,5-O-orthoformate → 1,3,5-tri-O-allyl-scyllo-inositol (865837-93-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium hydride / tetrahydrofuran / 0.33 h / 0 °C

1.2: dimethylformamide / 2 h / 20 °C

2.1: 100 percent / p-toluene sulfonic acid / methanol; ethyl acetate / 1 h / 20 °C

With sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethyl acetate;

DOI:10.1016/j.tetlet.2005.07.001

Reference yield:

2,4,6-tri-O-methyl-myo-inositol-1,3,5-orthoformate → 1,3,5-tri-O-allyl-scyllo-inositol (865837-93-0)

Guidance literature:

Multi-step reaction with 4 steps

1.1: 78.5 percent / PCC; molecular sieve 4A / CH₂Cl₂ / 16 h / Heating

2.1: 100 percent / NaBH₄ / methanol; tetrahydrofuran / 1 h / 20 °C

3.1: sodium hydride / tetrahydrofuran / 0.33 h / 0 °C

3.2: dimethylformamide / 2 h / 20 °C

4.1: 100 percent / p-toluene sulfonic acid / methanol; ethyl acetate / 1 h / 20 °C

With sodium tetrahydroborate; 4 A molecular sieve; sodium hydride; toluene-4-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate;

DOI:10.1016/j.tetlet.2005.07.001