ReBr(CO)2(NCtBu)(PPh(OEt)2)2

Base Information

Chemical Name:ReBr(CO)2(NCtBu)(PPh(OEt)2)2
CAS No.:1220455-93-5
Molecular Formula:C₂₇H₃₉BrNO₆P₂Re
Molecular Weight:801.668
Hs Code.:

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Chemical Property of ReBr(CO)2(NCtBu)(PPh(OEt)2)2

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Technology Process of ReBr(CO)2(NCtBu)(PPh(OEt)2)2

There total 1 articles about ReBr(CO)2(NCtBu)(PPh(OEt)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 49742-37-2,49742-45-2
mer,trans-[ReBr(CO)3(diethylphenylphosphonite)2]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 1220455-93-5
ReBr(CO)2(NCtBu)(PPh(OEt)2)2

Guidance literature:: In toluene; under Ar using standard Schlenk techniques or inert atmosphere dry-box; t-BuNC added to soln. of ReBr(CO)2(PPh(OEt)2)2 (4:2 mol) in toluene; reflux for 1 h; evapd. (vac.); residue treated (EtOH); stirred at 0°C; product filtered off; dried (vac.); elem. anal.;
DOI:10.1016/j.ica.2009.01.029

Reference yield: 84.0%

: 10025-69-1
tin(II) chloride dihdyrate

: 1220455-93-5
ReBr(CO)2(NCtBu)(PPh(OEt)2)2

: Re(SnCl₃)(CO)2(NCtBu)(PPh(OEt)2)2

Guidance literature:: In ethanol; under Ar using standard Schlenk techniques or inert atmosphere dry-box; soln. of SnCl2*2H2O in EtOH added to solid complex (6:1.5 mol); reflux for 2 h; evapd. (vac.); product filtered off; crystd. (CH2Cl2 and EtOH); elem. anal.;
DOI:10.1016/j.ica.2009.01.029