(Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde

Base Information

• Chemical Name: (Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde
• CAS No.: 1289574-10-2
• Molecular Formula: C₁₁H₉ClFeHgO
• Molecular Weight: 449.082
• Mol file: 1289574-10-2.mol

Synonyms:

Chemical Property of (Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde

There total 1 articles about (Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C5H5FeC5H3HgCl(COOCH2CH2CH2CH2OCH3) → (Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde (36473-76-4,1289574-10-2)

Guidance literature:

With p-CH₃C₆H₄SO₃H; H₂O; In dichloromethane; to Fe complex in CH2Cl2 added water and p-toluenesulfonic acid; mixt. stirred for 24 h; extd. with CH2Cl2, washed with water; org. layer dried with Na2SO4; solvent removed under reduced pressure; flash chromy. (silica, 4:1 hexanes:EtOAc) or recrystd. by layering CH2Cl2 soln. in hexanes;

DOI:10.1016/j.jorganchem.2010.12.042

Reference yield:

(Sp)-2-(chloromercurio)-ferrocenecarboxaldehyde (36473-76-4,1289574-10-2) + (R,R)-1,2-diphenylethylenediamine (35132-20-8) → (Sp,Sp,Rc,Rc)-N,N-bis(2-(chloromercurio)ferrocenylidene)-1,2-diphenylethane-1,2-diimine

Guidance literature:

In toluene; Fe complex, amine and toluene added to flask; activated alumina added; mixt. heated to 50°C, stirred for 24 h; filtered through celite; solvent removed under reduced pressure; oil dried under high vac., recrystd. by layering CH2Cl2 soln. with hexane;

DOI:10.1016/j.jorganchem.2010.12.042