Technology Process of C25H38O3
There total 8 articles about C25H38O3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane
2.1: chloro-trimethyl-silane; lithium diisopropyl amide / tetrahydrofuran
2.2: 12 h / Reflux
4.1: tetrabutyl ammonium fluoride
5.1: pyridine
6.1: potassium tert-butylate
7.1: lithium aluminium tetrahydride / diethyl ether / -20 °C
8.1: sodium hydrogencarbonate; Dess-Martin periodane
With
pyridine; dmap; lithium aluminium tetrahydride; chloro-trimethyl-silane; potassium tert-butylate; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; Dess-Martin periodane; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; dichloromethane;
2.1: Claisen rearrangement / 2.2: Claisen rearrangement / 8.1: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2010.11.012
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: chloro-trimethyl-silane; lithium diisopropyl amide / tetrahydrofuran
1.2: 12 h / Reflux
3.1: tetrabutyl ammonium fluoride
4.1: pyridine
5.1: potassium tert-butylate
6.1: lithium aluminium tetrahydride / diethyl ether / -20 °C
7.1: sodium hydrogencarbonate; Dess-Martin periodane
With
pyridine; lithium aluminium tetrahydride; chloro-trimethyl-silane; potassium tert-butylate; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; Dess-Martin periodane; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether;
1.1: Claisen rearrangement / 1.2: Claisen rearrangement / 7.1: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2010.11.012
- Guidance literature:
-
Multi-step reaction with 6 steps
2: tetrabutyl ammonium fluoride
3: pyridine
4: potassium tert-butylate
5: lithium aluminium tetrahydride / diethyl ether / -20 °C
6: sodium hydrogencarbonate; Dess-Martin periodane
With
pyridine; lithium aluminium tetrahydride; potassium tert-butylate; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; Dess-Martin periodane;
In
diethyl ether;
6: Dess-Martin oxidation;
DOI:10.1016/j.tetlet.2010.11.012