cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate

Base Information

Chemical Name:cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate
CAS No.:106417-87-2
Molecular Formula:BF₄*C₄₀H₄₃ClIrN₄P₂S₂
Molecular Weight:1020.37
Hs Code.:

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Chemical Property of cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate

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Technology Process of cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate

There total 1 articles about cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 110328-94-4
Ir(P(C₆H₅)3)2(Cl)(NCCH₃)2H⁽¹⁺⁾

: 13066-27-8
1,1-dimethyl-2-thioxohydrazine

: 106417-87-2
cis,trans-[chloro-hydrido-bis(thionitrosodimethylamino)-bis(triphenylphosphino)-iridium] tetrafluoroborate

Guidance literature:: With silver tetrafluoroborate; In tetrahydrofuran; diethyl ether; (N2), suspn. of the Ir-complex in acetonitrile treated with a soln. of AgBF4 in acetonitrile, refluxed for 15 min treated with an ethereal soln. of (CH3)2NNS, stirred for 15h; separated, toluene added, soln. reduced (vacuo), filtered off, washed (cold toluene,hexane), dissolved in CH2Cl2, chromd. (CH2Cl2/silica gel), crystd. (addn. of t-butanol), CH2Cl2 removed(reduced pressure), filteredoff, washed with ether, dried (vacuo);
DOI:10.1016/0022-328X(86)80415-6