{(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2}

Base Information

• Chemical Name: {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2}
• CAS No.: 147361-64-6
• Molecular Formula: C₄₂H₃₄Au₂P₂S₂
• Molecular Weight: 1058.74
• Mol file: 147361-64-6.mol

Synonyms:

Chemical Property of {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2}

There total 2 articles about {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + Benzene-1,2-dithiol (17534-15-5) → Au(S2C6H4)2(1-)*Au((C6H5)3P)2(1+) = {Au(S2C6H4)2}{Au(P(C6H5)3)2} + {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2} (147361-64-6)

Guidance literature:

With NaOH; In methanol; acetone; byproducts: NaCl; under inert atmosphere; a soln. of NaOH and 1,2-benzenedithiol added to a suspn. of Au-complex in acetone; evapd.; CH2Cl2 added; filtered off; washed with methanol and diethyl ether; dried in vacuo; elem. anal.;

Reference yield: 50.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + Benzene-1,2-dithiol (17534-15-5) → {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2} (147361-64-6)

Guidance literature:

With (C₂H₅)3N; In tetrahydrofuran; under dry and purified N2; at room temp. dropwise addn. of a mixt. of dithiol and Et3N in THF to a soln. of the Au-compd. (prepd. from PPh3 and HAuCl4) in THF with stirring (2 h); the ppt. is filtered off, recrystn. from CHCl3/hexane; elem. anal.;

Reference yield: 81.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + {(gold)2-(benzene-1,2-dithiolato)-(triphenylphosphine)2} (147361-64-6) + silver perchlorate → [Au3(S2C6H4)(P(C6H5)3)3](1+)*ClO4(1-) = [Au3(S2C6H4)(P(C6H5)3)3]ClO4 (156821-75-9)

Guidance literature:

In dichloromethane; N2, AgClO4 added to a soln. of ClAuPPh3, stirred for 1 h, filtered through Celite, dithiolate-complex added to the filtrate, stirred for 2 h; concd., Et2O added; elem. anal.;

upstream raw materials:

(triphenylphosphine)gold(I) chloride

Benzene-1,2-dithiol

Downstream raw materials:

[Au₃(S₂C₆H₄)(P(C₆H₅)3)3]⁽¹⁺⁾*ClO₄^(1-) = [Au₃(S₂C₆H₄)(P(C₆H₅)3)3]ClO₄

[Au2Ir(μ-S-S-benzenedithiolate)(η(4)-cyclooctadiene)(PPh3)2]BF4

[Au2Rh(μ-S-S-benzenedithiolate)(η(4)-cyclooctadiene)(PPh3)2]BF4