fac-tris(benzylisonitrile)tricarbonylmolybdenum

Base Information

• Chemical Name: fac-tris(benzylisonitrile)tricarbonylmolybdenum
• CAS No.: 109429-13-2
• Molecular Formula: C₂₇H₂₁MoN₃O₃
• Molecular Weight: 531.422
• Mol file: 109429-13-2.mol

Synonyms:

Chemical Property of fac-tris(benzylisonitrile)tricarbonylmolybdenum

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of fac-tris(benzylisonitrile)tricarbonylmolybdenum

There total 1 articles about fac-tris(benzylisonitrile)tricarbonylmolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

cobalt(II) chloride dihydrate + Benzyl isocyanide (88333-03-3,10340-91-7) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → fac-tris(benzylisonitrile)tricarbonylmolybdenum (109429-13-2,82269-81-6)

Guidance literature:

In toluene; soln. of Mo-compd. and CoCl2, reflux, 5min, oil bath, 120°C, cooled down to ca. 80°C, addn. of isonitrile, reflux; flash chromy. (methylene chloride - hexane 45:55); elem. anal.;

DOI:10.1021/ja00182a018

Reference yield:

fac-tris(benzylisonitrile)tricarbonylmolybdenum (109429-13-2,82269-81-6) + Benzyl isocyanide (88333-03-3,10340-91-7) → Mo(CO)2(C6H5CH2NC)4 (82284-02-4)

Guidance literature:

palladium(II) oxide; In toluene; equimolar amt. of reactants in toluene refluxed for 3 h;

DOI:10.1039/c39820000096

upstream raw materials:

Benzyl isocyanide

molybdenum hexacarbonyl

Downstream raw materials:

Mo(CO)2(C₆H₅CH₂NC)4