[η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2

Base Information

Chemical Name:[η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2
CAS No.:904319-51-3
Molecular Formula:C₃₈H₅₀B₁₀O₂P₂Ru
Molecular Weight:809.941
Hs Code.:

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Chemical Property of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2

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Technology Process of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2

There total 2 articles about [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 719-80-2
Ethyl diphenylphosphinite

: 805241-04-7
[η5:σ-Me2C(C5H4)(C2B10H10)]Ru(1,5-cyclooctadiene)

: 904319-51-3
[η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2

Guidance literature:: In tetrahydrofuran; under N2; THF soln. of Ru complex and PPh2(OEt) heated at reflux for 48 h; solvent removed; washed with n-hexane; recrystd. from THF at room temp.;elem. anal.;
DOI:10.1016/j.jorganchem.2006.03.022

Reference yield: 55.0%

: 109-72-8,29786-93-4
n-butyllithium

: 209164-07-8
Me₂C(C₅H₅)(C₂B₁₀H₁₁)

: 61863-69-2
RuCl₂(P(C₆H₅)2(OC₂H₅))3

: 904319-51-3
[η5:σ-Me2C(C5H4)(C2B10H10)]Ru(II)(ethyl diphenylphosphinite)2

Guidance literature:: In tetrahydrofuran; hexane; (N2); slow addn. of a soln. of n-BuLi in n-hexane to a soln. of boron compd. in THF at -78°C with stirring, warming to room temp., stirring for 3 h, addn. of ruthenium complex, stirring at room temp. for 24 h; evapn., addn. of CH2Cl2, filtration, evapn. in vac., recrystn. (THF);
DOI:10.1021/om0604122