[Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF₄

Base Information

• Chemical Name: [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF₄
• CAS No.: 1208231-55-3
• Molecular Formula: BF₄*C₆₁H₄₆CuN₄OP₂
• Molecular Weight: 1063.36
• Mol file: 1208231-55-3.mol

Synonyms:

Chemical Property of [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF₄

There total 2 articles about [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline (1208231-59-7) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4 (1208231-55-3)

Guidance literature:

In dichloromethane; mixt. Cu(MeCN)4BF4 (1 mol) and bis(2-(diphenylphosl)phenyl)oxide (1 mol)stirred for 1 h; 1-ethyl-2-(naphthalen-1-yl)-1H-imidazo(4,5-f)(1,10)phe nanthroline (1 mol) added; mixt. stirred for 1 h; solvent evapd.; TGA; elem. anal.;

DOI:10.1002/ejic.200900123

Reference yield:

copper(II) bis(tetrafluoroborate) + 1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline (1208231-59-7) + bis[2-(diphenylphosphino)phenyl] ether (166330-10-5) → [Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4 (1208231-55-3)

Guidance literature:

In not given; according to Zhang L., et al., Langmuir, 2009, 25, 2068; elem. anal.;

DOI:10.1016/j.saa.2012.04.011

Reference yield:

[Cu(1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline)(bis(2-(diphenylphosphanyl)phenyl) ether)]BF4 (1208231-55-3) → copper(I) tetrafluoroborate (14708-11-3)

Guidance literature:

In neat (no solvent); under N2; heating in TGA app. to 600°C;

DOI:10.1002/ejic.200900123

upstream raw materials:

1-ethyl-2-(naphthalen-1-yl)-1H-imidazo[4,5-f][1,10]phenanthroline

bis[2-(diphenylphosphino)phenyl] ether

Downstream raw materials:

copper(I) tetrafluoroborate