4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide

Base Information

• Chemical Name: 4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide
• CAS No.: 958248-52-7
• Molecular Formula: Br*C₂₈H₂₃N₄
• Molecular Weight: 495.421
• Mol file: 958248-52-7.mol

Synonyms:

Chemical Property of 4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide

There total 1 articles about 4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

4'-(4''-pyridyl)-2,2':6',2''-terpyridine (112881-51-3) + 4-Methylbenzyl bromide (104-81-4) → 4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide (958248-52-7)

Guidance literature:

In acetonitrile; Heating;

DOI:10.1039/b706419e

Reference yield: 71.0%

4-{[4'-(2,2':6',2-terpyridinyl)-1-pyridiniumyl]methyl}toluene bromide (958248-52-7) + ammonium hexafluorophosphate + [trichloro(4'-tolyl-2,2':6',2''-terpyridine)ruthenium(III)] (136276-24-9) → [(4'-(4-tolyl)-2,2':6',2''-terpyridine)Ru(4-([4'-(2,2':6',2''-terpyridinyl)-1-pyridiniumyl]methyl)toluene)](PF6)3

Guidance literature:

In ethanol; water; N,N-dimethyl-formamide; mixt. of Ru complex and ligand in EtOH/H2O/DMF (30:20:1) refluxed overnight, cooling to room temp., addn. of aq. NH4PF6; concn. under vac., addn. of H2O, filtration, ppt. sepd. and washed with EtOH and Et2O, recrystn. by diffusion of Et2O into soln. in MeCN; elem. anal.;

DOI:10.1039/b706419e

upstream raw materials:

4'-(4''-pyridyl)-2,2':6',2''-terpyridine

4-Methylbenzyl bromide