[1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2]

Base Information

• Chemical Name: [1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2]
• CAS No.: 448962-15-0
• Molecular Formula: C₈N₄NiS₄*C₁₂H₁₀BrFN
• Molecular Weight: 606.189
• Mol file: 448962-15-0.mol

Synonyms:

Chemical Property of [1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2]

There total 2 articles about [1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[1-(4'-bromo-2'-fluorobenzyl)pyridinium]2[Ni(maleonitriledithiolate)2] → [1-(4'-bromo-2'-fluorobenzyl)pyridinium][Ni(maleonitriledithiolate)2] (448962-15-0)

Guidance literature:

With iodine; In acetonitrile; a MeCN soln. of I2 was added to a soln. of Ni-complex in MeCN, mixt. wasstirred for 15 min; MeOH was added, mixt. was allowed to stand overnight, crystals were filtd. off, washed with MeOH, dried in vacuo; elem. anal.;

DOI:10.1039/b201936c

Reference yield:

2[BrC6H3(F)CH2NC5H5](1+)*[Ni((SCCN)2)2](2-)=[BrC6H3(F)CH2NC5H5]2[Ni((SCCN)2)2] → [BrC6H3(F)CH2NC5H5](1+)*[Ni((SCCN)2)2](1-)=[BrC6H3(F)CH2NC5H5][Ni((SCCN)2)2] (448962-15-0)

Guidance literature:

With I₂; In diethyl ether; acetonitrile; oxidation by I2 by dispersing Et2O in soln. of complex in MeCN for a wk;

DOI:10.1246/cl.2002.576

Refernces

• 1、 Xie, Jingli,Ren, Xiaoming,Song, You,Zou, Yang,Meng, Qingjin. "Synthesis, crystal structure and magnetic properties of a novel one-dimensional nickel(III) chain complex showing ferromagnetic ordering at low temperature". . p. 2868 - 2872. Retrieved 2002.