cis-3,trans-4-dibromocyclohexyl hydroperoxide

Base Information

• Chemical Name: cis-3,trans-4-dibromocyclohexyl hydroperoxide
• CAS No.: 80778-31-0
• Molecular Formula: C₆H₁₀Br₂O₂
• Molecular Weight: 273.952
• Mol file: 80778-31-0.mol

Synonyms:

Chemical Property of cis-3,trans-4-dibromocyclohexyl hydroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-3,trans-4-dibromocyclohexyl hydroperoxide

There total 8 articles about cis-3,trans-4-dibromocyclohexyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohex-3-enyl hydroperoxide (4096-33-7) → trans-3,cis-4-dibromocyclohexyl hydroperoxide (80778-31-0,80778-32-1) + cis-3,trans-4-dibromocyclohexyl hydroperoxide (80778-31-0,80778-32-1)

Guidance literature:

With bromine; In tetrachloromethane; at 0 ℃; Yield given. Yields of byproduct given;

DOI:10.1039/P19810003272

Reference yield:

cyclohex-3-enyl hydroperoxide (4096-33-7) → trans-3,cis-4-dibromocyclohexyl hydroperoxide (80778-31-0,80778-32-1) + cis-3,trans-4-dibromocyclohexyl hydroperoxide (80778-31-0,80778-32-1)

Guidance literature:

With bromine; In tetrachloromethane; at 0 ℃; Yield given. Yields of byproduct given;

DOI:10.1039/P19810003272

Reference yield:

cyclohex-3-enone (4096-34-8) → trans-3,cis-4-dibromocyclohexyl hydroperoxide (80778-31-0,80778-32-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 28.5 g / ethanol

2: NaBH₄ / methanol; H₂O / 0 °C

3: Na₂O₂, H₂O₂ / tetrahydrofuran

4: bromine / CCl₄ / 0 °C

With sodium tetrahydroborate; sodium peroxide; dihydrogen peroxide; bromine; In tetrahydrofuran; methanol; tetrachloromethane; ethanol; water;

DOI:10.1039/P19810003272

upstream raw materials:

cyclohex-3-enyl hydroperoxide

cyclohex-3-enone

Δ³-Cyclohexenon-p-toluolsulfonylhydrazon

Refernces