(cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeCl

Base Information

• Chemical Name: (cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeCl
• CAS No.: 1345823-94-0
• Molecular Formula: C₃₇H₄₇ClGeN₂
• Molecular Weight: 627.837
• Mol file: 1345823-94-0.mol

Synonyms:

Chemical Property of (cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeCl

There total 1 articles about (cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

germanium(II) chloride dioxane + C6H3(CH(CH3)2)2NHC6H8CC6H5NC6H3(CH(CH3)2)2 → (cyclo-C6H8-1-N(2,6-iPr2C6H3)-2-C(Ph)N(2,6-iPr2C6H3))GeCl (1345823-94-0)

Guidance literature:

In diethyl ether; byproducts: LiCl; (N2); addn. of Li compd. to a soln. of ligand in Et2O at -78°C, slow warming to room temp., stirring for 4 h, addn. of Ge compd. at -78°C, stirring overnight at room temp.; evapn. in vac., extn. with warm toluene, concn., cooling to -30°C; elem. anal.;

DOI:10.1021/om200970s

Reference yield: 78.0%

(cyclo-C6H8-1-N(2,6-iPr2C6H3)-2-C(Ph)N(2,6-iPr2C6H3))GeCl (1345823-94-0) → GeC6H3(CH(CH3)2)2NC6H7CC6H5NC6H3(CH(CH3)2)2 (1345823-95-1)

Guidance literature:

With 1,3-di-tert-butylimidazol-2-ylidene; In toluene; byproducts: 1,3-di-tert-butylimidazol-2-ylidene hydrochloride; (N2); stirring a soln. of Ge complex and carbene in toluene at room temp. for 48 h; evapn. in vac., extn. with warm hexane, concn., cooling to -30°C;elem. anal.;

DOI:10.1021/om200970s

Reference yield:

(cyclo-C6H8-1-N(2,6-iPr2C6H3)-2-C(Ph)N(2,6-iPr2C6H3))GeCl (1345823-94-0) → GeNH2C6H3(CH(CH3)2)2NC6H8CC6H5NC6H3(CH(CH3)2)2 (1345823-96-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1,3-di-tert-butylimidazol-2-ylidene / toluene

2: toluene

With 1,3-di-tert-butylimidazol-2-ylidene; In toluene;

DOI:10.1021/om200970s

Downstream raw materials:

GeC₆H₃(CH(CH₃)2)2NC₆H₇CC₆H₅NC₆H₃(CH(CH₃)2)2

GeNH₂C₆H₃(CH(CH₃)2)2NC₆H₈CC₆H₅NC₆H₃(CH(CH₃)2)2

(cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-CH(Ph)N(2,6-iPr₂C₆H₃))Ge

(cyclo-C₆H₈-1-N(2,6-iPr₂C₆H₃)-2-C(Ph)N(2,6-iPr₂C₆H₃))GeH